Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane

被引：125

作者：

Guo, Jun ^{[1
]}

Chen, Jianhui ^{[1
]}

Lu, Zhan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 26期

基金：

美国国家科学基金会;

关键词：

ENANTIOSELECTIVE BOROHYDRIDE REDUCTION; ALKENE HYDROBORATION; HYDROSILYLATION; IRON; CARBONYL; HYDROGENATION; COMPLEXES; ALKYNES; BORANE; CHEMO;

D O I：

10.1039/c5cc01084e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly enantioselective cobalt-catalyzed hydroboration reaction of aryl ketones with HBpin was developed using iminopyridine oxazoline ligands. Halides, amines, ethers, sulfides, esters and amides are well tolerated under the mild reaction conditions, demonstrating its synthetic advantage. Substituted diaryl ketones could also be hydroborated with high enantioselectivity.

引用

页码：5725 / 5727

页数：3

共 50 条

[41] Application of Pinacolborane in Catalytic Enantioselective Hydroboration of Ketones and Imines
Liu, Wenbo
Lu, Zhan
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (11) : 3596 - 3604
[42] Cobalt-Catalyzed Reduction of Aldehydes to Alcohols via the Hydroboration Reaction
Lewandowski, Dariusz
Hreczycho, Grzegorz
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2024, 25 (14)
[43] Cobalt-Catalyzed Borylation of Aryl Halides and Pseudohalides
Yao, Wubing
Fang, Huaquan
Peng, Sihan
Wen, Huanan
Zheng, Lei
Hu, Aiguo
Huang, Zheng
ORGANOMETALLICS, 2016, 35 (10) : 1559 - 1564
[44] Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides
Jiang, Xuan
Jiang, Hao
Yang, Qian
Cheng, Ying
Lu, Liang-Qiu
Tunge, Jon A.
Xiao, Wen-Jing
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (18) : 8347 - 8354
[45] Cobalt-Catalyzed Protodeboronation of Aryl and Vinyl Boronates
Li, Ninglin
Xiong, Fuqiang
Gao, Ke
JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (02): : 1972 - 1979
[46] Cobalt-catalyzed annulation of aryl iodides with alkynes
Komeyama, Kimihiro
Kashihara, Tetsuya
Takaki, Ken
TETRAHEDRON LETTERS, 2013, 54 (42) : 5659 - 5662
[47] Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides
Zhu Ziqi
Shi Zhuangzhi
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2022, 42 (06) : 1872 - 1874
[48] Photoassisted Cobalt-Catalyzed Asymmetric Reductive Grignard-Type Addition of Aryl Iodides
Jiang, Xuan
Jiang, Hao
Yang, Qian
Cheng, Ying
Lu, Liang-Qiu
Tunge, Jon A.
Xiao, Wen-Jing
Journal of the American Chemical Society, 2022, 144 (18): : 8347 - 8354
[49] A highly efficient cobalt-catalyzed deuterogenolysis of diboron: Synthesis of deuterated pinacolborane and vinylboronates
Qiao, Lin
Zhang, Lei
Liu, Guixia
Huang, Zheng
TETRAHEDRON, 2019, 75 (31) : 4138 - 4142
[50] Zinc Catalyzed Hydroboration of Esters and Nitriles with Pinacolborane
Kumar, Gobbilla Sai
Kumar, Ravi
Sau, Abhijit
Chandrasekhar, Vadapalli
Panda, Tarun K.
JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (17): : 12613 - 12622

← 1 2 3 4 5 →