Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane

被引：125

作者：

Guo, Jun ^{[1
]}

Chen, Jianhui ^{[1
]}

Lu, Zhan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 26期

基金：

美国国家科学基金会;

关键词：

ENANTIOSELECTIVE BOROHYDRIDE REDUCTION; ALKENE HYDROBORATION; HYDROSILYLATION; IRON; CARBONYL; HYDROGENATION; COMPLEXES; ALKYNES; BORANE; CHEMO;

D O I：

10.1039/c5cc01084e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly enantioselective cobalt-catalyzed hydroboration reaction of aryl ketones with HBpin was developed using iminopyridine oxazoline ligands. Halides, amines, ethers, sulfides, esters and amides are well tolerated under the mild reaction conditions, demonstrating its synthetic advantage. Substituted diaryl ketones could also be hydroborated with high enantioselectivity.

引用

页码：5725 / 5727

页数：3

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