What is the surface specific area of porous cement-based material? A nuclear magnetic relaxation dispersion approach

We propose a new NMR method to measure and follow the evolution of the surface specific area, S,,, of a porous cement-based material. This method, that does not require any preliminary drying process, uses nuclear magnetic relaxation dispersion (NMRD), the measurement of spin-lattice relaxation rate as a function of magnetic field strength or nuclear Larmor frequency. The method is applied for three different mortars samples prepared by mixing cement, sand, silica fume, water and superplasticizer with a water to cement ratio w/c = 0.25, 0.38 and 0.65, respectively. The evolution of S-P grows linearly with the degree of advancement of chemical reactions measured by thermal heating and we evidence two relaxation processes independent of the w/c ratio. (C) 2003 Elsevier Science Inc. All rights reserved.