The Study of Self-Oscillations During CH4 Oxidation Over Ni by the Pulse Method: Is it Possible?

被引：11
|
作者：
Bychkov, V. Yu. [1 ]
Tulenin, Yu. P. [1 ]
Slinko, M. M. [1 ]
Gorenberg, A. Ya. [1 ]
Korchak, V. N. [1 ]
机构：
[1] Russian Acad Sci, Semenov Inst Chem Phys, GSP-1,Kosygina Str 4, Moscow 119991, Russia
来源：
CATALYSIS LETTERS | 2017年 / 147卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
Heterogeneous catalysis; Catalysis; Oscillations; Methodology and phenomena; Mass spectrometry; Microscopy; Spectroscopy and general characterization; Oxidation; Processes and reactions; METHANE OXIDATION; TEMPERATURE OSCILLATIONS; NICKEL-CATALYST; BEHAVIOR; SIMULATION; SURFACES; ORIGIN;
D O I：
10.1007/s10562-017-2167-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
For the first time, the pulse method has been applied to the study of the self-oscillatory behaviour. For methane oxidation over Ni foil the response to a sequence of equal pulses has been strictly periodic. The pulse method allowed to obtain some new information about the origin of oscillations in this reaction.
引用
收藏
页码：2664 / 2673
页数：10
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