The Study of Self-Oscillations During CH4 Oxidation Over Ni by the Pulse Method: Is it Possible?

被引：11

作者：

Bychkov, V. Yu. ^{[1
]}

Tulenin, Yu. P. ^{[1
]}

Slinko, M. M. ^{[1
]}

Gorenberg, A. Ya. ^{[1
]}

Korchak, V. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, GSP-1,Kosygina Str 4, Moscow 119991, Russia

来源：

CATALYSIS LETTERS | 2017年 / 147卷 / 10期

基金：

俄罗斯科学基金会;

关键词：

Heterogeneous catalysis; Catalysis; Oscillations; Methodology and phenomena; Mass spectrometry; Microscopy; Spectroscopy and general characterization; Oxidation; Processes and reactions; METHANE OXIDATION; TEMPERATURE OSCILLATIONS; NICKEL-CATALYST; BEHAVIOR; SIMULATION; SURFACES; ORIGIN;

D O I：

10.1007/s10562-017-2167-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

For the first time, the pulse method has been applied to the study of the self-oscillatory behaviour. For methane oxidation over Ni foil the response to a sequence of equal pulses has been strictly periodic. The pulse method allowed to obtain some new information about the origin of oscillations in this reaction.

引用

页码：2664 / 2673

页数：10

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