A Photodynamic Library of Tetrasulfinylcalix[4]arenes: The Sulfinyl Dance

被引：8

作者：

Cacciapaglia, Roberta ^{[1
,2
]}

Di Stefano, Stefano ^{[1
,2
]}

Lanzalunga, Osvaldo ^{[1
,2
]}

Maugeri, Leonardo ^{[1
,2
]}

Mazzonna, Marco ^{[1
,2
]}

机构：

[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy

[2] CNR, IMC, I-00185 Rome, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 2012卷 / 07期

关键词：

Sulfoxides; Combinatorial chemistry; Calixarenes; Photochemistry; Isomerization; SULFUR;

D O I：

10.1002/ejoc.201101699

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photoinversion of sulfoxides has been exploited to generate a photodynamic combinatorial library (PDCL) of tetrasulfinylcalix[4]arenes. Irrespective of the starting isomer, the same product distribution is obtained at the photostationary state upon irradiation at a given wavelength. The order of appearance of the different isomers in the reaction mixture plays a key role in the disclosure of the identity of all the isomers of the PDCL.

引用

页码：1426 / 1430

页数：5

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