Transparent red -emitting silicone resin for color conversion and encapsulation of NUV light-emitting diodes

被引:6
作者
Chen, Hong [1 ]
Wang, Yao [1 ]
Lin, Jianhui [1 ]
Shuai, Minmin [1 ]
Zhu, Haidi [1 ]
Zhang, Wengong [1 ]
Ling, Qidan [1 ]
机构
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Key Lab Polymer Mat, Fuzhou, Fujian, Peoples R China
基金
中国国家自然科学基金;
关键词
exfoliation; layered double hydroxides; light-emitting diodes; silicone; LAYERED DOUBLE HYDROXIDES; HIGH REFRACTIVE-INDEX; SILOXANE HYBRID; ENERGY-STORAGE; NANOSHEETS; PURITY;
D O I
10.1111/jace.16140
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Herein, a novel transparent phenyl vinyl silicone resin nanocomposite containing exfoliated fluorescent Eu-containing hydrotalcite-like compound (EFHSN) is developed to serve as a dual role of color conversion and encapsulation material. Excited by near-NUV light, the EFHSN emits a strong characteristic red light (614 nm). Meanwhile, the EFHSN shows not only excellent transparency (T > 95%) in the UV-Vis region and high refractive index (1.46) but also superior thermal stability, which could meet the need of commercial encapsulation materials and optical application. Therefore, the EFHSN is expected to be used in InGaN-based NUV light-emitting diodes and flexible optoelectronic device.
引用
收藏
页码:2718 / 2726
页数:9
相关论文
共 32 条
[1]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[2]   A review on Mn4+ activators in solids for warm white light-emitting diodes [J].
Chen, Daqin ;
Zhou, Yang ;
Zhong, Jiasong .
RSC ADVANCES, 2016, 6 (89) :86285-86296
[3]   White-light hydrotalcite-like compound emission from the incorporation of red-, green-, and blue-emitting metal complexes [J].
Chen, Hong ;
Zhang, WenGong ;
Lin, ZhengHuan ;
Ling, QiDan .
OPTICAL MATERIALS EXPRESS, 2013, 3 (01) :105-113
[4]   Synthesis and characterization of a strong-fluorescent Eu-containing hydrotalcite-like compound [J].
Chen Hong ;
Zhang WenGong .
SCIENCE CHINA-CHEMISTRY, 2010, 53 (06) :1273-1280
[5]   Thermochemistry of europium and dithiocarbamate complex Eu(C5H8NS2)3(C12H8N2) [J].
Chen, S. P. ;
Meng, X. X. ;
Shuai, Q. ;
Jiao, B. J. ;
Gao, S. L. ;
Shi, Q. Z. .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2006, 86 (03) :767-774
[6]   Broad near-ultraviolet and blue excitation band induced dazzling red emissions in Eu3+-activated Gd2MoO6 phosphors for white light-emitting diodes [J].
Du, Peng ;
Guo, Yue ;
Lee, Soo Hyun ;
Yu, Jae Su .
RSC ADVANCES, 2017, 7 (06) :3170-3178
[7]   Measurement of absolute photoluminescence quantum yields using integrating spheres - Which way to go? [J].
Faulkner, Daniel O. ;
McDowell, Jeffrey J. ;
Price, Alastair J. ;
Perovic, Doug D. ;
Kherani, Nazir P. ;
Ozin, Geoffrey A. .
LASER & PHOTONICS REVIEWS, 2012, 6 (06) :802-806
[8]   Poly(styrenesulfonate)-Modified Ni-Ti Layered Double Hydroxide Film: A Smart Drug-Eluting Platform [J].
Ge, Naijian ;
Wang, Donghui ;
Peng, Feng ;
Li, Jinhua ;
Qiao, Yuqin ;
Liu, Xuanyong .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (37) :24491-24501
[9]   Luminescent and thermal properties of a novel red-emitting silicon fluoride acrylate-Eu(III) copolymer for white LEDs [J].
Hu, Jun ;
Xu, Lin ;
Xu, Lei ;
Tsuboi, Taiju ;
Huang, Wei ;
Xie, Hongde .
MATERIALS CHEMISTRY AND PHYSICS, 2014, 147 (03) :777-782
[10]  
Huang Wei, 2006, [Adhesion and lnterface, 접착 및 계면], V7, P39