The L-Leu Hexamer, a Short and Highly Enantioselective Peptide Catalyst for the Julia-Colonna Epoxidation: Stabilization of a Helical Conformation in DMSO

被引：24

作者：

Weyer, Alexandra ^{[1
]}

Diaz, Dolores ^{[2
]}

Nierth, Alexander ^{[1
]}

Schloerer, Nils E. ^{[1
]}

Berkessel, Albrecht ^{[1
]}

机构：

[1] Univ Cologne, Dept Chem, D-50939 Cologne, Germany

[2] CSIC, Dept Biol Fisicoquim, Ctr Invest Biol, E-28040 Madrid, Spain

来源：

CHEMCATCHEM | 2012年 / 4卷 / 03期

关键词：

enantioselectivity; epoxidation; molecular dynamics; NMR spectroscopy; organocatalysis; PHASE-BOUND PEPTIDES; ENONE EPOXIDATION; DYNAMICS; OLIGOPEPTIDES; PROTEINS; PROGRAM;

D O I：

10.1002/cctc.201100243

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

[No abstract available]

引用

页码：337 / 340

页数：4

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