Structure-directing role of hydrogen-bonded dimers of phenylenediammonium cations: Supramolecular assemblies of octamolybdate-based organic-inorganic hybrids

被引：47

作者：

Upreti, S ^{[1
]}

Ramanan, A ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Delhi, Hauz Khas, India

来源：

CRYSTAL GROWTH & DESIGN | 2005年 / 5卷 / 05期

关键词：

D O I：

10.1021/cg050100m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystallization of three new organic/inorganic hybrid solids (1-3) based on octamolybdate under self-assembly conditions has demonstrated the structure-directing role of three hydrogen-bonded organic dimers (supramolecular synthons) in the construction of multidimensional networks. In acidified aqueous molybdate solution, isomeric phenylenediammonium ions form dimers through strong hydrogen-bonding and/or pi-pi interactions, which in turn dictate the supramolecular assemblies between themselves or with octamolybdate anions that eventually result in the growth of hybrid solids.

引用

页码：1837 / 1843

页数：7

共 38 条

[1] ORGANIC-INORGANIC CHARGE-TRANSFER SALTS BASED ON THE BETA-[MO8O26]4- ISOPOLYANION - SYNTHESIS, PROPERTIES AND X-RAY STRUCTURE [J].

ATTANASIO, D ;

BONAMICO, M ;

FARES, V ;

SUBER, L .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (16) :2523-2528

[2]

Desiraju G. R., 1999, WEAK HYDROGEN BOND S

[3]

Desiraju G. R., 1989, DESIGN ORGANIC SOLID

[4] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

[5] Two new inorganic-organic hybrid salts:: [NH2Me2]4[NMe4]2-[Mo0.5O4⊂(Mo12O36)]•1.5H2O and [NMe4]2[NH4]2[Mo8O26]•2H2O [J].

Duraisamy, T ;

Ramanan, A ;

Vittal, JJ .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (03) :763-767

[6] MOLYBDATES OF AROMATIC HETEROCYCLIC-COMPOUNDS - SYNTHESIS AND STRUCTURE OF AN OCTAMOLYBDATE CONTAINING COORDINATELY BOUND PYRAZOLE - [(C3H4N2)2(MO8O26)]4- [J].

GILI, P ;

MARTINZARZA, P ;

MARTINREYES, G ;

ARRIETA, JM ;

MADARIAGA, G .

POLYHEDRON, 1992, 11 (01) :115-121

[7]

Hagman P. J., 1999, ANGEW CHEM INT EDIT, V38, P2638

[8] Polyoxomolybdate clusters and copper-organonitrogen complexes as building blocks for the construction of composite solids [J].

Hagrman, D ;

Hagrman, P ;

Zubieta, J .

INORGANICA CHIMICA ACTA, 2000, 300 :212-224

[9] Tris(piperazinium) octamolybdate, (C4H12N2)(3)[Mo8O27] [J].

Harrison, WTA ;

Dussack, LL ;

Jacobson, AJ .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :1075-1077

[10]

KAMENAR B, 1990, KEM IND, V39, P185

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