Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites

被引：2
作者：
Mandal, Debdas [1 ]
Haldar, Anwesha [1 ]
Chakraborty, Priyanka [1 ]
Ganguly, Rakesh [2 ]
机构：
[1] Sidho Kanho Birsha Univ, Dept Chem, Purulia 723104, W Bengal, India
[2] Shiv Nadar Univ, Dept Chem, Gautam Buddha Nagar 201314, Uttar Pradesh, India
来源：
MOLBANK | 2022年 / 2022卷 / 03期
关键词：
mixed-ligand complex; crystal structure; hydrogen interaction; Hirshfeld surface analysis; CATECHOL OXIDASE ACTIVITY; SCHIFF-BASE COMPLEXES; IRON(III) COMPLEXES; MODELS; RELEVANCE; PROGRAM;
D O I：
10.3390/M1447
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A mononuclear octahedral mixed-ligand cobalt (II) complex [Co(H2L)(PhCOO)(2)] (1) has been prepared by using H2L (N,N'-dimethyl-N,N'-bi(2-hydroxy-3,5-di methyl benzyl)-ethylenediamine) as a facially coordinating tetradentate ligand with a N2O2 donor center along with sodium benzoate as an ancillary ligand. Complex 1 has been characterized by a single-crystal X-ray diffraction study, as well as by other spectroscopic tools. The complex crystallizes in the monoclinic space group C-2 with a = 31.73(3) angstrom, b = 7.868(3) angstrom, c = 19.131(15) angstrom, and beta = 125.25(3)degrees. The single-crystal X-ray diffraction study shows that in the mononuclear cobalt (II) complex [Co(H2L)(PhCOO)(2)] (1), the metal center adopts an octahedral environment.
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页数：8
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共 27 条
  • [1] Mono and tri-nuclear cobalt(III) complexes with sterically constrained phenol based N2O2 ligand: Synthesis, structure and catechol oxidase activity
    Ali, Imran
    Mandal, Bikramaditya
    Saha, Rajat
    Ghosh, Rajarshi
    Majee, Mithun Chandra
    Mondal, Dhrubajyoti
    Mitra, Partha
    Mandal, Debdas
    [J]. POLYHEDRON, 2020, 180
  • [2] [Anonymous], 2021, APEX4 VERSION 2021
  • [3] Electronic and steric effects in manganese Schiff-base complexes as models for the water oxidation complex in photosystem II. The isolation of manganese-(II) and -(III) complexes of 3- and 3,5-substituted N,N'-bis(salicylidene)ethane-1,2-diamine (H(2)salen) ligands
    Bermejo, MR
    Castineiras, A
    GarciaMonteagudo, JC
    Rey, M
    Sousa, A
    Watkinson, M
    McAuliffe, CA
    Pritchard, RG
    Beddoes, RL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (14): : 2935 - 2944
  • [4] SYNTHESIS OF MO(IV) AND MO(V) COMPLEXES USING OXO ABSTRACTION BY PHOSPHINES - MECHANISTIC IMPLICATIONS
    CHEN, GJJ
    MCDONALD, JW
    NEWTON, WE
    [J]. INORGANIC CHEMISTRY, 1976, 15 (11) : 2612 - 2615
  • [5] Metal-Salen Schiff base complexes in catalysis: practical aspects
    Cozzi, PG
    [J]. CHEMICAL SOCIETY REVIEWS, 2004, 33 (07) : 410 - 421
  • [6] Synthesis and second-order nonlinear optical properties of bis(salicylaldiminato)M(II) metalloorganic materials
    Di Bella, S
    Fragalà, I
    [J]. SYNTHETIC METALS, 2000, 115 (1-3) : 191 - 196
  • [7] CATALYTIC ASYMMETRIC OXIDATIONS USING OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES AS CATALYSTS
    KATSUKI, T
    [J]. COORDINATION CHEMISTRY REVIEWS, 1995, 140 : 189 - 214
  • [8] Lacroix PG, 2001, EUR J INORG CHEM, P339
  • [9] Synthesis, structure, Hirshfeld surface analysis and catecholase activity of Ni(II) complex with sterically constrained phenol based ligand
    Mandal, Bikramaditya
    Majee, Mithun Chandra
    Mandal, Debdas
    Ganguly, Rakesh
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2020, 1202 (1202)
  • [10] Synthesis, structure, DFT study and catechol oxidase activity of Cu(II) complex with sterically constrained phenol based ligand
    Mandal, Bikramaditya
    Majee, Mithun Chandra
    Rakshit, Trilochan
    Banerjee, Snehasis
    Mitra, Partha
    Mandal, Debdas
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2019, 1193 : 265 - 273
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