Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites

被引：2

作者：

Mandal, Debdas ^{[1
]}

Haldar, Anwesha ^{[1
]}

Chakraborty, Priyanka ^{[1
]}

Ganguly, Rakesh ^{[2
]}

机构：

[1] Sidho Kanho Birsha Univ, Dept Chem, Purulia 723104, W Bengal, India

[2] Shiv Nadar Univ, Dept Chem, Gautam Buddha Nagar 201314, Uttar Pradesh, India

来源：

MOLBANK | 2022年 / 2022卷 / 03期

关键词：

mixed-ligand complex; crystal structure; hydrogen interaction; Hirshfeld surface analysis; CATECHOL OXIDASE ACTIVITY; SCHIFF-BASE COMPLEXES; IRON(III) COMPLEXES; MODELS; RELEVANCE; PROGRAM;

D O I：

10.3390/M1447

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mononuclear octahedral mixed-ligand cobalt (II) complex [Co(H2L)(PhCOO)(2)] (1) has been prepared by using H2L (N,N'-dimethyl-N,N'-bi(2-hydroxy-3,5-di methyl benzyl)-ethylenediamine) as a facially coordinating tetradentate ligand with a N2O2 donor center along with sodium benzoate as an ancillary ligand. Complex 1 has been characterized by a single-crystal X-ray diffraction study, as well as by other spectroscopic tools. The complex crystallizes in the monoclinic space group C-2 with a = 31.73(3) angstrom, b = 7.868(3) angstrom, c = 19.131(15) angstrom, and beta = 125.25(3)degrees. The single-crystal X-ray diffraction study shows that in the mononuclear cobalt (II) complex [Co(H2L)(PhCOO)(2)] (1), the metal center adopts an octahedral environment.

引用

页数：8

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