Novel Nanoporous Carbon/Iron Oxide Catalyst for SO2 Degradation

被引:2
作者
Stanisavljevic, Maja [1 ]
Jankovic, Savka [1 ]
Milisavic, Dragana [1 ]
Cado, Marko [2 ]
Kukric, Zoran [2 ]
Stevic, Dragana [3 ]
Kukobat, Radovan [3 ]
Ilic, Predrag [4 ]
Meded, Denis [4 ]
Wojtan, Magdalena Parlinska [5 ]
Atlagic, Suzana Gotovac [1 ]
机构
[1] Univ Banja Luka, Fac Nat Sci & Math, Mladena Stojanovica 2, Banja Luka 78000, Bosnia & Herceg
[2] Univ Banja Luka, Fac Technol, Bulevar Vojvode Stepe Stepanovica 73, Banja Luka 78000, Bosnia & Herceg
[3] Shinshu Univ, Ctr Energy & Environm Sci, Wakasato 4-17-1, Nagano 3808553, Japan
[4] Inst Protect & Ecol Republ Srpska, Vidovdanska 43, Banja Luka 78000, Bosnia & Herceg
[5] Polish Acad Sci, Inst Nucl Phys, PL-31342 Krakow, Poland
关键词
active carbon; mining sludge; metal remediation; organometallic materials; SO2; filtration; POLYCYCLIC AROMATIC-HYDROCARBONS; FLUE-GAS DESULFURIZATION; ACTIVATED CARBON; TEMPORAL SCALES; AIR; ADSORPTION; NOX;
D O I
10.1016/j.matpr.2018.12.095
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A green chemistry approach for fabrication of active carbon, enriched with remediated iron is shown. Detailed characterization (HRSTEM, STM, and N-2 adsorption) was performed, followed by active carbon soaking in iron and manganese ionic solutions obtained from remediated mining sludge. Novel forms of active carbons with round or needle-like oxide particles on the surface were obtained by combining these materials. The materials were tested as filters for sulfur dioxide, on sulfur-rich coals fume. After adsorption, the iron structures seem to play a stronger catalytic role in the filter regeneration, transforming the adsorbed sulfur dioxide into sulfuric acid. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:920 / 929
页数:10
相关论文
共 25 条
[1]   Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: A review [J].
Abioye, Adekunle Moshood ;
Ani, Farid Nasir .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 52 :1282-1293
[2]  
[Anonymous], 2007, 15259 EN IDT
[3]  
Atlagic S. G., 2018, COMMER NANOTECHNOLOG, P299
[4]   An overview of the modification methods of activated carbon for its water treatment applications [J].
Bhatnagar, Amit ;
Hogland, William ;
Marques, Marcia ;
Sillanpaa, Mika .
CHEMICAL ENGINEERING JOURNAL, 2013, 219 :499-511
[5]   Adsorption of gases in multimolecular layers [J].
Brunauer, S ;
Emmett, PH ;
Teller, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :309-319
[6]  
Clesceri L.S., 1998, STANDARD METHODS EXA, V20th
[7]   Status of Flue Gas Desulphurisation (FGD) systems from coal-fired power plants: Overview of the physic-chemical control processes of wet limestone FGDs [J].
Cordoba, Patricia .
FUEL, 2015, 144 :274-286
[8]   SO2 and NOx adsorption properties of activated carbons obtained from a pitch containing iron derivatives [J].
Davini, P .
CARBON, 2001, 39 (14) :2173-2179
[9]   Quantification of sources of PCBs to the atmosphere in urban areas: A comparison of cities in North America, Western Europe and former Yugoslavia [J].
Gasic, Bojan ;
MacLeod, Matthew ;
Klanova, Jana ;
Scheringer, Martin ;
Ilic, Predrag ;
Lammel, Gerhard ;
Pajovic, Aleksandar ;
Breivik, Knut ;
Holoubek, Ivan ;
Hungerbuehler, Konrad .
ENVIRONMENTAL POLLUTION, 2010, 158 (10) :3230-3235
[10]  
Ibanez E. Fernandez, 2003, THESIS