Isothermal vapour-liquid equilibria in the binary and ternary systems composed of 2,2,4-trimethylpentane, 2-methyl-1-propanol, and 4-methyl-2-pentanone

被引：3

作者：

Bernatova, Svatoslava ^{[1
]}

Pavlicek, Jan ^{[1
]}

Wichterle, Ivan ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, Vvi, CR-16502 Prague 6, Czech Republic

来源：

FLUID PHASE EQUILIBRIA | 2011年 / 307卷 / 01期

关键词：

Vapour-liquid equilibrium; Experimental data; Prediction; Hydrocarbon; Alcohol; Ketone; 3-METHYL-2-BUTANONE; 2-PROPANOL; ETHER;

D O I：

10.1016/j.fluid.2011.05.011

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapour-liquid equilibrium data in the three binary 2,2,4-trimethylpentane + 2-methyl-1-propanol, 2-methyl-1-propanol + 4-methyl-2-pentanone, 2,2,4-trimethylpentane + 4-methyl-2-pentanone systems, and in the ternary 2,2,4-trimethylpentane + 2-methyl-1-propanol + 4-methyl-2-pentanone system are reported. The data were measured isothermally at 333.15, 348.15 and 364.15 K covering the pressure range 12-100 kPa. The binary vapour-liquid equilibrium data were correlated using the Wilson and NRTL equations by means of a robust algorithm for processing all isotherms together: resulting parameters were then used for calculation of phase behaviour in the ternary system and for subsequent comparison with experimental data. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：66 / 71

页数：6

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