Microwave-assisted synthesis of mesoporous metal-organic framework NH2-MIL-101(Al)

被引：20

作者：

Isaeva, V. I. ^{[1
]}

Tarasov, A. L. ^{[1
]}

Starannikova, L. E. ^{[2
]}

Yampol'skii, Yu. P. ^{[2
]}

Alent'ev, A. Yu. ^{[2
]}

Kustov, L. M. ^{[1
,3
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prosp, Moscow 119991, Russia

[2] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Chem Dept, Moscow 119992, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 12期

基金：

俄罗斯科学基金会;

关键词：

metal-organic frameworks; mesopores; nanoparticles; morphology; microwave activation; mixed matrix membranes; nanofiller; gas permeability; MIXED MATRIX MEMBRANES; GAS SEPARATION; DESIGN;

D O I：

10.1007/s11172-015-1227-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The possibility of formation of the mixed matrix membranes NH2-MIL-101(Al) under the conditions of microwave activation of the reaction mixture at atmospheric pressure is studied. Microwave irradiation affects the morphology and crystallite size and significantly shortens the synthesis time (from tens of hours to 10-30 min). The obtained samples of NH2-MIL-101(Al) with a crystallite size of 100 nm were used as nanofillers for polymer matrix based on the PIM-1 polymer with intrinsic microporosity for the preparation of hybrid membrane materials. Gas permeability for a series of gases was measured on the synthesized membranes.

引用

页码：2791 / 2795

页数：5

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