Synthesis and Characterization of Some Metal Complexes of Isonitroso-2-acetylnaphthalene Derivative

被引:2
作者
Ucan, S. Y. [1 ]
Ucan, M. [1 ]
Demir, I. [1 ]
机构
[1] Nigde Univ, Fac Arts & Sci, Dept Chem, TR-51200 Nigde, Turkey
关键词
isonitroso-2-acetylnaphthalene; Schiff bases; metal chelates; SCHIFF-BASE LIGAND; COPPER(II) COMPLEXES; CRYSTAL-STRUCTURE; NICKEL(II); COBALT(II); ZINC(II); CADMIUM(II); EXTRACTION; CU(II); CO(II);
D O I
10.1134/S1070363216080235
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nickel(II), copper(II), and zinc(II) complexes with the Schiff base obtained from isonitroso-2-acetylnaphthalene and 1,2-phenylenediamine were synthesized. The compounds were characterized by elemental analyses, FT-IR, UV-Vis, and H-1 and C-13 NMR spectra, conductance measurements, magnetic susceptibility measurements, and thermal analysis. The results suggest tetradentate coordination of the symmetrical Schiff base ligand through the two oxime oxygen atoms and two azomethine nitrogen atoms. The molar conductance data showed that the synthesized complexes are non-electrolytes.
引用
收藏
页码:1917 / 1921
页数:5
相关论文
共 19 条
[1]   Tetranuclear nickel complex of dimethylene bridged diiminedioxime containing different hybridizations of nickel (II) [J].
Achiwawanich, Supakit ;
Duangthongyou, Tanwawan ;
Kitiphaisalnont, Panana ;
Siripaisarnpipat, Sutatip .
JOURNAL OF MOLECULAR STRUCTURE, 2014, 1072 :149-152
[2]   Preparation, structures an properties of dinuclear and trinuclear copper(II) complexes bridged by one oximato and one hydroxo ligands [J].
Akagi, F ;
Michihiro, Y ;
Nakao, Y ;
Matsumoto, K ;
Sato, T ;
Mori, W .
INORGANICA CHIMICA ACTA, 2004, 357 (03) :684-688
[3]   Synthesis, characterization and extraction studies of some metal (II) complexes containing (hydrazoneoxime and bis-acylhydrazone) moieties [J].
Al-Ne'aimi, Mohammed Mahmmod ;
Al-Khuder, Mohammed Moudar .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 105 :365-373
[4]   A Co(III) complex with a tridentate amine-imine-oxime ligand from 1,2,3,4-tetrahydroquinazoline: synthesis, crystal structure, spectroscopic and thermal characterization [J].
Colak, Alper Tolga ;
Irez, Gazi ;
Mutlu, Hasene ;
Hokelek, Tuncer ;
Caylak, Nagihan .
JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (06) :1005-1014
[5]   Synthesis, structure, and solvent-extraction properties of tridentate oxime ligands and their cobalt(II), nickel(II), copper(II), zinc(II) complexes [J].
Dede, Buelent ;
Karipcin, Fatma ;
Arabali, Filiz ;
Cengiz, Mustafa .
CHEMICAL PAPERS, 2010, 64 (01) :25-33
[6]   Synthesis, spectral characterization, solution equilibria, in vitro antibacterial and cytotoxic activities of Cu(II), Ni(II), Mn(II), Co(II) and Zn(II) complexes with Schiff base derived from 5-bromosalicylaldehyde and 2-aminomethylthiophene [J].
Ei-Sherif, Ahmed A. ;
Eldebss, Taha M. A. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 79 (05) :1803-1814
[7]   Stabilization of the trivalent oxidation state of copper by tridentate imine-oxime-amine ligands [J].
Eltayeb, Mohamed A. -Z. ;
Sulfab, Yousif .
POLYHEDRON, 2007, 26 (01) :1-5
[8]   Synthesis and characterization of Co(II), Ni(II), Zn(II) and Cu(II) complexes with a new tetraazamacrocyclic Schiff base ligand containing a piperazine moiety: X-ray crystal structure determination of the Co(II) complex [J].
Keypour, Hassan ;
Rahpeyma, Nasibeh ;
Arzhangi, Parisa ;
Rezaeivala, Majid ;
Elerman, Yalcin ;
Buyukgungor, Orhan ;
Valencia, Laura .
POLYHEDRON, 2010, 29 (03) :1144-1148
[9]   Synthesis, spectral characterization and electrochemical properties of new vic-dioxime complexes bearing carboxylate [J].
Kilic, Ahmet ;
Tas, Esref ;
Gumgum, Bahattin ;
Yilmaz, Ismail .
TRANSITION METAL CHEMISTRY, 2006, 31 (05) :645-652
[10]   Synthesis of Schiff base ligands derived from condensation of salicylaldehyde derivatives and synthetic diamine [J].
Naeimi, Hossein ;
Safari, Javad ;
Heidarnezhad, Arash .
DYES AND PIGMENTS, 2007, 73 (02) :251-253