Ion pair receptors based on anion-π interaction

被引：76
作者：
Chen, Yin [1 ]
Wang, De-Xian [1 ]
Huang, Zhi-Tang [1 ]
Wang, Mei-Xiang [1 ,2 ]
机构：
[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
[2] Tsinghua Univ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Dept Chem, Beijing 100084, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期
关键词：
SELECTIVE RECOGNITION; HALIDE RECOGNITION; HOST MOLECULES; SODIUM-CYANIDE; COMPLEXES; RINGS;
D O I：
10.1039/c1cc12075a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel type of ditopic ion pair receptors based on anion-p interaction is reported. Oxacalix[2]arene[2]triazine azacrowns were synthesized efficiently from a one-pot reaction between 2,4-dichloro-4-methoxytriazine and 3,5-dihydroxybenzaldehyde followed by condensation with a diamine and reduction of bisimine; they acted as selective ditopic receptors to recognize ion pairs.
引用
收藏
页码：8112 / 8114
页数：3
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