A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior

被引：21
作者：
Hamasaka, Go [1 ]
Muto, Tsubasa [1 ,2 ]
Uozumi, Yasuhiro [1 ,2 ,3 ]
机构：
[1] Inst Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Grad Sch Adv Studies, Okazaki, Aichi 4448787, Japan
[3] RIKEN, Wako, Saitama 3510198, Japan
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 35期
关键词：
VESICLES; ACIDS;
D O I：
10.1039/c1dt10556f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated.
引用
收藏
页码：8859 / 8868
页数：10
相关论文
共 22 条
  • [1] Vesicles and organogels from foldamers: A solvent-modulated self-assembling process
    Cai, Wei
    Wang, Gui-Tao
    Xu, Yun-Xiang
    Jiang, Xi-Kui
    Li, Zhan-Ting
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (22) : 6936 - +
  • [2] Frisch M., 2004, GAUSSIAN 03 REVISION, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014
  • [3] Molecular-Architecture-Based Administration of Catalysis in Water: Self-Assembly of an Amphiphilic Palladium Pincer Complex
    Hamasaka, Go
    Muto, Tsubasa
    Uozumi, Yasuhiro
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (21) : 4876 - 4878
  • [4] Self-assembled hexa-peri-hexabenzocoronene graphitic nanotube
    Hill, JP
    Jin, WS
    Kosaka, A
    Fukushima, T
    Ichihara, H
    Shimomura, T
    Ito, K
    Hashizume, T
    Ishii, N
    Aida, T
    [J]. SCIENCE, 2004, 304 (5676) : 1481 - 1483
  • [5] Direct visualization of efficient energy transfer in single oligo(p-phenylene vinylene) vesicles
    Hoeben, FJM
    Shklyarevskiy, IO
    Pouderoijen, MJ
    Engelkamp, H
    Schenning, LPHJ
    Christianen, PCM
    Maan, JC
    Meijer, EW
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (08) : 1232 - 1236
  • [6] Jeon YJ, 2002, ANGEW CHEM INT EDIT, V41, P4474, DOI 10.1002/1521-3773(20021202)41:23<4474::AID-ANIE4474>3.0.CO
  • [7] 2-S
  • [8] Synthesis of [2,6-bis(2-oxazolinyl)phenyl]palladium complexes via the ligand introduction route
    Kimura, Tsutomu
    Uozumi, Yasuhiro
    [J]. ORGANOMETALLICS, 2008, 27 (19) : 5159 - 5162
  • [9] PCP pincer palladium complexes and their catalytic properties: Synthesis via the electrophilic ligand introduction route
    Kimura, Tsutomu
    Uozumi, Yasuhiro
    [J]. ORGANOMETALLICS, 2006, 25 (20) : 4883 - 4887
  • [10] Room-temperature discotic nematic liquid crystals over a wide temperature range: Alkali-metal-ion-induced phase transition from discotic nematic to columnar phases
    Kohmoto, Shigeo
    Mori, Emiko
    Kishikawa, Keiki
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (44) : 13364 - +
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