Synthesis and characterization of a Mo/Ag/Rb heterotrimetallic cluster with double-cage architecture

被引:10
作者
Lin, P [1 ]
Clegg, W [1 ]
Harrington, RW [1 ]
Henderson, RA [1 ]
机构
[1] Univ Newcastle Upon Tyne, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
关键词
D O I
10.1039/b503447g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first Mo/ Ag/ Rb heterotrimetallic cluster has been synthesised by a self- assembly reaction involving [ Mo(2)O(2)S(2)edt(2)](2-), Ag+, Rb+, S2- and dibenzo- 18- crown- 6 ( DB18C6); the structure consists of two [{Mo(6)Ag(6)O(6)S(7)edt(6)} 2{Rb( DB18C6)}] (3-) units linked by Rb - C contacts.
引用
收藏
页码:2349 / 2351
页数:3
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