Room temperature synthesis and characterization of polythiophene thin films by chemical bath deposition (CBD) method

被引:20
作者
Kamat, Sandip V. [1 ]
Puri, Vijaya [2 ]
Puri, R. K. [1 ]
机构
[1] Shivaji Univ, Vacuum Tech & Thin Film Lab, USIC, Kolhapur 416004, Maharashtra, India
[2] Shivaji Univ, Dept Phys, Kolhapur 416004, Maharashtra, India
关键词
Polymers; Chemical synthesis; Infrared spectroscopy; Optical properties; POLYMERIZATION;
D O I
10.1016/j.matchemphys.2011.11.044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polythiophene thin films were deposited successfully on glass substrate by chemical bath deposition method using FeCl3 as an oxidant and chloroform as solvent. The effect of oxidant concentration on the properties of polythiophene thin films was studied. The surface morphology was influenced by oxidant concentration and deposition time. The oxidation concentration also strongly affects the optical properties of the polythiophene thin films. The transmittance decreases while the absorption, band gap and refractive index increases due to increase in oxidant concentration. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:228 / 232
页数:5
相关论文
共 15 条
  • [1] Synthesis and characterization of soluble polythiophene derivatives containing electron-transporting moiety
    Ahn, SH
    Czae, MZ
    Kim, ER
    Lee, H
    Han, SH
    Noh, J
    Hara, M
    [J]. MACROMOLECULES, 2001, 34 (08) : 2522 - 2527
  • [2] Matrix-assisted pulsed laser evaporation of polythiophene films
    Bloisi, F.
    Cassinese, A.
    Papa, R.
    Vicari, L.
    Califano, V.
    [J]. THIN SOLID FILMS, 2008, 516 (07) : 1594 - 1598
  • [3] SPECTROSCOPIC AND ELECTRICAL CHARACTERIZATION OF SOME ANILINE OLIGOMERS AND POLYANILINE
    CAO, Y
    LI, SZ
    XUE, ZJ
    GUO, D
    [J]. SYNTHETIC METALS, 1986, 16 (03) : 305 - 315
  • [4] SnO2 substrate effects on the morphology and composition of chemical bath deposited ZnSe thin films
    Chaparro, AM
    Martínez, MA
    Guillén, C
    Bayón, R
    Gutiérrez, MT
    Herrero, J
    [J]. THIN SOLID FILMS, 2000, 361 : 177 - 182
  • [5] Daik R., 2007, MALAYSIAN J CHEM, V9, P16
  • [6] Synthesis and characterization of polythiophenes prepared in the presence of surfactants
    Gok, Aysegul
    Omastova, Maria
    Yavuz, Ayse Gul
    [J]. SYNTHETIC METALS, 2007, 157 (01) : 23 - 29
  • [7] Synthesis and characterization of a dye-functionalized polythiophene with different chromic properties
    Goncalves, Vanessa C.
    Balogh, Debora T.
    [J]. EUROPEAN POLYMER JOURNAL, 2006, 42 (12) : 3303 - 3310
  • [8] Band gap shift, structural characterization and phase transformation of CdSe thin films from nanocrystalline cubic to nanorod hexagonal on air annealing
    Kale, RB
    Lokhande, CD
    [J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2005, 20 (01) : 1 - 9
  • [9] A facile synthesis of polythiophene nanowires
    Karim, Mohammad Rezaul
    Lim, Kwon Taek
    Lee, Chul Jae
    Lee, Mu Sang
    [J]. SYNTHETIC METALS, 2007, 157 (22-23) : 1008 - 1012
  • [10] Kukla A.L., 2006, THERO EXP CHEM, V42, P339