Zinc(II) and cobalt(II) complexes with 3,5-di( pyridine-4-yl)benzoate: Structure and property

被引：9
作者：
Hou, Chao [1 ]
Zhao, Yue [1 ]
Lu, Yi [1 ]
Wang, Peng [1 ]
Sun, Wei-Yin [1 ]
机构：
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Inst Coordinat Chem,State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 20卷
基金：
中国国家自然科学基金;
关键词：
Zn(II) and Co(II) complexes; hxl net; Crystal structure; Fluorescence property; Antiferromagnetic interaction; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; SUPRAMOLECULAR STRUCTURES; II COMPLEXES; LIGAND; CONNECTIVITY; TEMPERATURE; COPPER(II); TRANSITION; ADSORPTION;
D O I：
10.1016/j.inoche.2012.03.039
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal complexes with different 2D network topologies based on the 3,5-di(pyridine-4-yl)benzoic acid (HL), namely {[Zn(L)(2)]center dot 0.86H(2)O}(n) (1) and {[Co-2(L)(3)(H2O)(2)]ClO4}(n) (2), have been prepared and characterized by single crystal and powder X-ray diffractions. IR, and thermogravimetric analyses. Complex 1 has a typical sql topology, whereas complex 2 is an unusual hxl one. Moreover, complex 1 shows luminescent property in the solid state at room temperature, and 2 exhibits overall weak antiferromagnetic coupling between the adjacent Co(II) ions. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：317 / 321
页数：5
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