Zinc(II) and cobalt(II) complexes with 3,5-di( pyridine-4-yl)benzoate: Structure and property

被引：9
作者：
Hou, Chao [1 ]
Zhao, Yue [1 ]
Lu, Yi [1 ]
Wang, Peng [1 ]
Sun, Wei-Yin [1 ]
机构：
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Inst Coordinat Chem,State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 20卷
基金：
中国国家自然科学基金;
关键词：
Zn(II) and Co(II) complexes; hxl net; Crystal structure; Fluorescence property; Antiferromagnetic interaction; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; SUPRAMOLECULAR STRUCTURES; II COMPLEXES; LIGAND; CONNECTIVITY; TEMPERATURE; COPPER(II); TRANSITION; ADSORPTION;
D O I：
10.1016/j.inoche.2012.03.039
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal complexes with different 2D network topologies based on the 3,5-di(pyridine-4-yl)benzoic acid (HL), namely {[Zn(L)(2)]center dot 0.86H(2)O}(n) (1) and {[Co-2(L)(3)(H2O)(2)]ClO4}(n) (2), have been prepared and characterized by single crystal and powder X-ray diffractions. IR, and thermogravimetric analyses. Complex 1 has a typical sql topology, whereas complex 2 is an unusual hxl one. Moreover, complex 1 shows luminescent property in the solid state at room temperature, and 2 exhibits overall weak antiferromagnetic coupling between the adjacent Co(II) ions. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：317 / 321
页数：5
相关论文
共 42 条
[1]   Influence of connectivity and porosity on ligand-based luminescence in zinc metal-organic frameworks [J].
Bauer, Christina A. ;
Timofeeva, Tatiana V. ;
Settersten, Thomas B. ;
Patterson, Brian D. ;
Liu, Vincent H. ;
Simmons, Blake A. ;
Allendorf, Mark D. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (22) :7136-7144
[2]   POLYNUCLEAR COMPLEXES WITH HYDROGEN-BONDED BRIDGES - DINUCLEAR COMPLEX OF N,N'-BIS(2-HYDROXYETHYL)-2,4-PENTANEDIIMINE WITH COPPER(II) [J].
BERTRAND, JA ;
BLACK, TD ;
ELLER, PG ;
HELM, FT ;
MAHMOOD, R .
INORGANIC CHEMISTRY, 1976, 15 (12) :2965-2970
[3]   Synthesis, structures, and magnetic properties of the copper(II), cobalt(II), and manganese(II) complexes with 9-acridinecarboxylate and 4-quinolinecarboxylate ligands [J].
Bu, XH ;
Tong, ML ;
Xie, YB ;
Li, JR ;
Chang, HC ;
Kitagawa, S ;
Ribas, J .
INORGANIC CHEMISTRY, 2005, 44 (26) :9837-9846
[4]   A series of novel entangled coordination frameworks with inherent features of self-threading, polyrotaxane and polycatenane [J].
Chen, Haiyan ;
Xiao, Dongrong ;
He, Jianghong ;
Li, Zhifu ;
Zhang, Guangju ;
Sun, Dianzhen ;
Yuan, Ruo ;
Wang, Enbo ;
Luo, Qun-Li .
CRYSTENGCOMM, 2011, 13 (15) :4988-5000
[5]   Two zinc-triazole-biphenyldicarboxylate coordination polymers affording a 3D 4-connected 2-fold interpenetrating diamond net and a 2D 6-connected hxl net [J].
Chen, Yanli ;
Fan, Yong ;
Zhang, Daojun ;
Huang, Liangliang ;
Jiang, Jinhua ;
Zhang, Ping ;
Xu, Jianing .
INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (02) :343-346
[6]   A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].
Chui, SSY ;
Lo, SMF ;
Charmant, JPH ;
Orpen, AG ;
Williams, ID .
SCIENCE, 1999, 283 (5405) :1148-1150
[7]   Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures [J].
Dai, JC ;
Wu, XT ;
Fu, ZY ;
Cui, CP ;
Hu, SM ;
Du, WX ;
Wu, LM ;
Zhang, HH ;
Sun, RO .
INORGANIC CHEMISTRY, 2002, 41 (06) :1391-1396
[8]   Early-late transition metal ferromagnetic coupling mediated by hydrogen bonding [J].
Desplanches, U ;
Ruiz, E ;
Alvarez, S .
CHEMICAL COMMUNICATIONS, 2002, (22) :2614-2615
[9]   Molecular tectonics of mixed-ligand metal-organic frameworks: Positional isomeric effect, metal-directed assembly, and structural diversification [J].
Du, Miao ;
Jiang, Xiu-Juan ;
Zhao, Xiao-Jun .
INORGANIC CHEMISTRY, 2007, 46 (10) :3984-3995
[10]   Adsorption of gases and vapors on nanoporous Ni2(4,4′-bipyridine)3(NO3)4 metal-organic framework materials templated with methanol and ethanol:: Structural effects in adsorption kinetics [J].
Fletcher, AJ ;
Cussen, EJ ;
Bradshaw, D ;
Rosseinsky, MJ ;
Thomas, KM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (31) :9750-9759
12345