cis-aquabis(2,2′-bipyridine-N,N′)[dichromato(2-)-O 1]nickel(II)

被引:1
作者
Fernández-González, L
González-Silgo, C
González-Platas, J
Gili, P
Martín-Zarza, P
机构
[1] Univ La Laguna, Dpto Fis Fundamental 2, E-38204 La Laguna, Tenerife, Spain
[2] Univ La Laguna, Dpto Quim Inorgan, E-38204 La Laguna, Tenerife, Spain
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词
D O I
10.1107/S1600536800020389
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The molecular structure of the title compound, [Ni(C10H8N2)(2) (H2O){Cr2O7}], contains an Ni-II atom with a distorted cis-octahedral coordination formed by two chelating bipyridine (bipy) ligands [mean Ni-N-bipy = 2.068 (3) Angstrom], one water molecule [Ni-O = 2.086 (3) Angstrom] and an O atom of the dichromate anion [Ni-O = 2.083 (2) Angstrom]. One of the water H atoms is involved in the intramolecular hydrogen bond with the terminal O atom of the dichromate ligand [O . . .O 2.743 (5) Angstrom], whereas its second H atom participates in the intermolecular hydrogen bonding [O . . .O 2.688 (4) Angstrom]; the latter is responsible for the formation of the infinite chains stretching along the polar c axis of the crystal.
引用
收藏
页码:M43 / M45
页数:3
相关论文
共 23 条
[1]   SIR97:: a new tool for crystal structure determination and refinement [J].
Altomare, A ;
Burla, MC ;
Camalli, M ;
Cascarano, GL ;
Giacovazzo, C ;
Guagliardi, A ;
Moliterni, AGG ;
Polidori, G ;
Spagna, R .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119
[2]   SIGNIFICANT ANTIFERROMAGNETIC COUPLING IN A TEREPHTHALATE (TA)-BRIDGED MANGANESE(II) COMPOUND - PREPARATION, CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF THE CHAIN [MN-2(BIPY)(4)(TA)][CLO4](2) (BIPY=2,2'-BIPYRIDINE) [J].
CANO, J ;
DEMUNNO, G ;
SANZ, J ;
RUIZ, R ;
LLORET, F ;
FAUS, J ;
JULVE, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (23) :3465-3469
[3]   CRYSTAL-STRUCTURE AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF 2 CIS-AZIDO CATENAS OF NICKEL(II) - CIS-CATENA-MU-N3)[NI(BIPY)2](X) (X=CLO4, PF6) [J].
CORTES, R ;
URTIAGA, K ;
LEZAMA, L ;
PIZARRO, JL ;
GONI, A ;
ARRIORTUA, MI ;
ROJO, T .
INORGANIC CHEMISTRY, 1994, 33 (18) :4009-4015
[4]   A UNIQUE BRIDGING DICHROMATE LIGAND IN [MN2(CR2O7)2(BPY)4] (BPY=2,2'-BIPYRIDINE) [J].
DAVE, BC ;
CZERNUSZEWICZ, RS .
INORGANIC CHEMISTRY, 1994, 33 (05) :847-848
[5]  
Enraf-Nonius, 1994, CAD 4 EXPRESS
[6]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[7]   Compounds of chromium(VI) as ligands [J].
Gili, P ;
Lorenzo-Luis, PA .
COORDINATION CHEMISTRY REVIEWS, 1999, 193-5 :747-768
[8]  
GILI P, 1999, COORDIN CHEM REV, P193
[9]   Crystal structure and magnetic properties of the single-μ-chloro copper(II) chain [Cu(bipy)Cl2] (bipy = 2,2′-bipyridine) [J].
Hernández-Molina, M ;
González-Platas, J ;
Ruiz-Pérez, C ;
Lloret, F ;
Julve, M .
INORGANICA CHIMICA ACTA, 1999, 284 (02) :258-265
[10]   MU-DICHROMATO(VI)-O,O'-BIS(ETHYLENEDIAMINE)COPPER(II) - STRUCTURE, THERMOCHEMISTRY AND MAGNETIC-SUSCEPTIBILITY [J].
JAMESON, GB ;
SEFERIADIS, N ;
OSWALD, HR .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :984-987