Single-molecule magnets:: Ligand-induced core distortion and multiple Jahn-Teller isomerism in [Mn12O12(O2CMe)8(O2PPh2)8(H2O)4]

被引：141
作者：
Boskovic, C
Pink, M
Huffman, JC
Hendrickson, DN [1 ]
Christou, G
机构：
[1] Univ Calif San Diego, Dept Chem 0358, La Jolla, CA 92093 USA
[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
[3] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 40期
关键词：
D O I：
10.1021/ja016341+
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：9914 / 9915
页数：2
相关论文
共 11 条
[1]   Single-molecule magnets:: Jahn-Teller isomerism and the origin of two magnetization relaxation processes in Mn12 complexes [J].
Aubin, SMJ ;
Sun, ZM ;
Eppley, HJ ;
Rumberger, EM ;
Guzei, IA ;
Folting, K ;
Gantzel, PK ;
Rheingold, AL ;
Christou, G ;
Hendrickson, DN .
INORGANIC CHEMISTRY, 2001, 40 (09) :2127-2146
[2]   Reduced anionic Mn12 molecules with half-integer ground states as single-molecule magnets [J].
Aubin, SMJ ;
Sun, ZM ;
Pardi, L ;
Krzystek, J ;
Folting, K ;
Brunel, LC ;
Rheingold, AL ;
Christou, G ;
Hendrickson, DN .
INORGANIC CHEMISTRY, 1999, 38 (23) :5329-5340
[3]   Single-molecule magnets [J].
Christou, George ;
Gatteschi, Dante ;
Hendrickson, David N. ;
Sessoli, Roberta .
MRS Bulletin, 2000, 25 (11) :66-71
[4]   HIGH-SPIN MOLECULES - UNUSUAL MAGNETIC-SUSCEPTIBILITY RELAXATION EFFECTS IN [MN12O12(O(2)CET)(16)(H2O)(3)] (S=9) AND THE ONE-ELECTRON REDUCTION PRODUCT (PPH4)[MN12O12(O(2)CET)(16)(H2O)(4)] (S=19/2) [J].
EPPLEY, HJ ;
TSAI, HL ;
DEVRIES, N ;
FOLTING, K ;
CHRISTOU, G ;
HENDRICKSON, DN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :301-317
[5]   Steps in the hysteresis loops of a high-spin molecule [J].
Friedman, JR ;
Sarachik, MP ;
Tejada, J ;
Maciejewski, J ;
Ziolo, R .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (08) :6031-6033
[6]   MAGNETIC BISTABILITY IN A METAL-ION CLUSTER [J].
SESSOLI, R ;
GATTESCHI, D ;
CANESCHI, A ;
NOVAK, MA .
NATURE, 1993, 365 (6442) :141-143
[7]   HIGH-SPIN MOLECULES - [MN12O12(O2CR)16(H2O)4] [J].
SESSOLI, R ;
TSAI, HL ;
SCHAKE, AR ;
WANG, SY ;
VINCENT, JB ;
FOLTING, K ;
GATTESCHI, D ;
CHRISTOU, G ;
HENDRICKSON, DN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (05) :1804-1816
[8]   A third isolated oxidation state for the Mn12 family of single-molecule magnets [J].
Soler, M ;
Chandra, SK ;
Ruiz, D ;
Davidson, ER ;
Hendrickson, DN ;
Christou, G .
CHEMICAL COMMUNICATIONS, 2000, (24) :2417-2418
[9]   The origin of the second relaxation process in the [Mn12O12(O2CR)16(H2O)4] single-molecule magnets:: 'Jahn-Teller isomerism' in the [Mn12O12] core [J].
Sun, ZM ;
Ruiz, D ;
Dilley, NR ;
Soler, M ;
Ribas, J ;
Folting, K ;
Maple, MB ;
Christou, G ;
Hendrickson, DN .
CHEMICAL COMMUNICATIONS, 1999, (19) :1973-1974
[10]   Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets [J].
Thomas, L ;
Lionti, F ;
Ballou, R ;
Gatteschi, D ;
Sessoli, R ;
Barbara, B .
NATURE, 1996, 383 (6596) :145-147
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