Molecular dynamics in a new solid glucofuranose-based low-molecular-weight organogelator as studied by 1H NMR

被引：6

作者：

Bielejewski, M. ^{[1
]}

Rachocki, A. ^{[1
]}

Luboradzki, R. ^{[2
]}

Tritt-Goc, J. ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Mol Phys, PL-60179 Poznan, Poland

[2] Polish Acad Sci, Inst Phys Chem, Warsaw, Poland

来源：

APPLIED MAGNETIC RESONANCE | 2008年 / 33卷 / 04期

关键词：

D O I：

10.1007/s00723-008-0081-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The proton spin-lattice relaxation time T-1 and the nuclear magnetic resonance second moment were used to study the molecular dynamics of 1,2-O-(1-ethylpropylidene)-alpha-D-glucofuranose, a new low-molecular-weight organogelator, in the temperature range of 85-308 K. The observed T-1 minima were attributed to the motion of methyl groups. The experimental data were interpreted in terms of Haupt's theory assuming the tunneling-assisted relaxation process.

引用

页码：431 / 438

页数：8

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