Well-defined copper(I) complexes for Click azide-alkyne cycloaddition reactions: one Click beyond

被引：171

作者：

Diez-Gonzalez, Silvia ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2011年 / 1卷 / 02期

关键词：

HUISGEN 1,3-DIPOLAR CYCLOADDITION; ONE-POT SYNTHESIS; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; CATALYZED CYCLOADDITION; EFFICIENT SYNTHESIS; TERMINAL ALKYNES; REGIOSELECTIVE SYNTHESIS; BLOCK-COPOLYMERS; SULFONYL AZIDES; AMIDE SYNTHESIS;

D O I：

10.1039/c0cy00064g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The discovery of copper(I) species as excellent catalysts for the regioselective cycloaddition reactions of azides and alkynes served as proof-of-concept of the importance of Click chemistry and opened a broad field of research that has found numerous ramifications in biochemistry, materials and medicinal science, for instance. The use of ligands in this context not only serves to stabilize the oxidation state of copper, but has also been shown to increase and modulate its reactivity. Still, efforts focused on developing more efficient catalytic systems for this transformation remain limited. Herein, the catalytic activities of ligated copper systems are reviewed in a way intended inspirational for further developments.

引用

页码：166 / 178

页数：13

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