One-pot synthesis of imidazoles from aromatic nitriles with nickel catalysts

被引：32

作者：

Garcia, Juventino J. ^{[1
]}

Zerecero-Silva, Paulina ^{[1
]}

Reyes-Rios, Grisell ^{[1
]}

Crestani, Marco G. ^{[1
]}

Arevalo, Alma ^{[1
]}

Barrios-Francisco, Rigoberto ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Fac Quim, Mexico City 04510, DF, Mexico

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 36期

关键词：

CARBON-CARBON BONDS; COMPLEXES; BENZONITRILE; CLEAVAGE;

D O I：

10.1039/c1cc13497c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nickel(0) catalysts were used to produce substituted imidazoles in good to high yields using benzonitrile, p-substituted benzonitriles and 4-cyanopyridine as starting materials.

引用

页码：10121 / 10123

页数：3

共 14 条

[1] Bond Activation with Low-Valent Nickel in Homogeneous Systems [J].

Arevalo, Alma ;

Garcia, Juventino J. .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (26) :4063-4074

[2] Reactions of benzonitrile with diiodides of neodymium, dysprosium, and thulium [J].

Balashova, TV ;

Khoroshenkov, GV ;

Kusyaev, DM ;

Eremenko, LL ;

Aleksandrov, GG ;

Fukin, GK ;

Bochkarev, MN .

RUSSIAN CHEMICAL BULLETIN, 2004, 53 (04) :825-829

[3] Regioselective Functionalization of the Imidazole Ring via Transition Metal-Catalyzed C-N and C-C Bond Forming Reactions [J].

Bellina, Fabio ;

Rossi, Renzo .

ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (08) :1223-1276

[4] IMINO CARBENE COMPLEXES OF TUNGSTEN AND CHROMIUM AS SYNTHONS FOR NITRILE YLIDES IN REACTIONS WITH ALKYNES, ALKENES, NITRILES, AND ALDEHYDES [J].

DRAGISICH, V ;

WULFF, WD ;

HOOGSTEEN, K .

ORGANOMETALLICS, 1990, 9 (11) :2867-2870

[5] HEXAAMMINE COMPLEXES OF COPPER(2) ION [J].

ELLIOTT, H ;

HATHAWAY, BJ .

INORGANIC CHEMISTRY, 1966, 5 (05) :885-&

[6] Cleavage of carbon-carbon bonds in aromatic nitriles using nickel(0) [J].

Garcia, JJ ;

Brunkan, NM ;

Jones, WD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) :9547-9555

[7] Reversible cleavage of carbon-carbon bonds in benzonitrile using nickel(0) [J].

Garcia, JJ ;

Jones, WD .

ORGANOMETALLICS, 2000, 19 (26) :5544-5545

[8] Structural and functional aspects of metal sites in biology [J].

Holm, RH ;

Kennepohl, P ;

Solomon, EI .

CHEMICAL REVIEWS, 1996, 96 (07) :2239-2314

[9] Fluoro aromatic imine nickel(0) complexes:: Synthesis and structural studies [J].

Iglesias, Ana L. ;

Munoz-Hernandez, Miguel ;

Garcia, Juventino J. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (16) :3498-3507

[10] Homogeneous hydrogenation of fluoroaromatic imines with Ni compounds, evidence for η2-C=N intermediate in the catalytic cycle [J].

Iglesias, Ana L. ;

Garcia, Juventino J. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 298 (1-2) :51-59

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