Synthesis gas production process for natural gas conversion over Ni-La2O3 catalyst

被引:9
作者
Cho, Wonjun [1 ]
Yu, Hyejin [1 ,2 ]
Ahn, Wha-Seung [2 ]
Kim, Seung-Soo [3 ]
机构
[1] KOGAS, DME Technol Res Ctr, Inchon 406130, South Korea
[2] Inha Univ, Dept Chem Engn, Inchon 402751, South Korea
[3] Kangwon Natl Univ, Dept Chem Engn, Samcheok 245711, Gangwon Do, South Korea
关键词
Syngas; Steam-CO2 reforming (SCR); Synthetic fuel reactor; Catalyst; Kinetics; METHANE; CO2; CHALLENGES; REACTOR; COKE;
D O I
10.1016/j.jiec.2015.02.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis gas (syngas) is a mixture of hydrogen and carbon monoxide, which is suitable as a feed gas to produce clean liquid synthetic fuel in natural gas conversion reactor. In order to achieve the efficiency reactor, the syngas composition should match the usage ratio of the reactors. In this work, we investigate the development of synthesis gas production process in the steam-CO2 reforming (SCR) over Ni-La2O3 catalyst supported Ce-ZrO2/Al2O3. And, we developed the kinetics model for SCR used by the profiles of concentration and temperature in the SCR reactor. (C) 2015 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:229 / 235
页数:7
相关论文
共 24 条
[1]   Catalysis research of relevance to carbon management: Progress, challenges, and opportunities [J].
Arakawa, H ;
Aresta, M ;
Armor, JN ;
Barteau, MA ;
Beckman, EJ ;
Bell, AT ;
Bercaw, JE ;
Creutz, C ;
Dinjus, E ;
Dixon, DA ;
Domen, K ;
DuBois, DL ;
Eckert, J ;
Fujita, E ;
Gibson, DH ;
Goddard, WA ;
Goodman, DW ;
Keller, J ;
Kubas, GJ ;
Kung, HH ;
Lyons, JE ;
Manzer, LE ;
Marks, TJ ;
Morokuma, K ;
Nicholas, KM ;
Periana, R ;
Que, L ;
Rostrup-Nielson, J ;
Sachtler, WMH ;
Schmidt, LD ;
Sen, A ;
Somorjai, GA ;
Stair, PC ;
Stults, BR ;
Tumas, W .
CHEMICAL REVIEWS, 2001, 101 (04) :953-996
[2]   Steady-state kinetics and mechanism of methane reforming with steam and carbon dioxide over Ni catalyst [J].
Avetisov, A. K. ;
Rostrup-Nielsen, J. R. ;
Kuchaev, V. L. ;
Hansen, J. -H. Bak ;
Zyskin, A. G. ;
Shapatina, E. N. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 315 (02) :155-162
[3]  
Cho Wonjun, 2014, [Transactions of the Korean Hydrogen and New Energy Society, 한국수소및신에너지학회논문집], V25, P105, DOI 10.7316/KHNES.2014.25.2.105
[4]   Optimal design and operation of a natural gas tri-reforming reactor for DME synthesis [J].
Cho, Wonjun ;
Song, Taekyong ;
Mitsos, Alexander ;
McKinnon, J. Thomas ;
Ko, Glen H. ;
Tolsma, John E. ;
Denholm, Douglas ;
Park, Taeshin .
CATALYSIS TODAY, 2009, 139 (04) :261-267
[5]   Simulation of the catalytic partial oxidation of methane to synthesis gas [J].
DeGroote, AM ;
Froment, GF .
APPLIED CATALYSIS A-GENERAL, 1996, 138 (02) :245-264
[6]   Thermoneutral tri-reforming of flue gases from coal- and gas-fired power stations [J].
Halmann, M ;
Steinfeld, A .
CATALYSIS TODAY, 2006, 115 (1-4) :170-178
[7]   Modeling of a catalytic autothermal methane reformer for fuel cell applications [J].
Hoang, DL ;
Chan, SH .
APPLIED CATALYSIS A-GENERAL, 2004, 268 (1-2) :207-216
[8]  
조원준, 2009, [Applied Chemistry for Engineering, 공업화학], V20, P355
[9]   A highly effective and stable nano-sized Ni/MgO-Al2O3 catalyst for gas to liquids (GTL) process [J].
Koo, Kee Young ;
Roh, Hyun-Seog ;
Seo, Yu Taek ;
Seo, Dong Joo ;
Yoon, Wang Lai ;
Park, Seung Bin .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (08) :2036-2043
[10]   Coke study on MgO-promoted Ni/Al2O3 catalyst in combined H2O and CO2 reforming of methane for gas to liquid (GTL) process [J].
Koo, Kee Young ;
Roh, Hyun-Seog ;
Seo, Yu Taek ;
Seo, Dong Joo ;
Yoon, Wang Lai ;
Park, Seung Bin .
APPLIED CATALYSIS A-GENERAL, 2008, 340 (02) :183-190