Tuning the solubility of polymerized ionic liquids by simple anion-exchange reactions

被引:326
作者
Marcilla, R
Blazquez, JA
Rodriguez, J
Pomposo, JA
Mecerreyes, D [1 ]
机构
[1] CIDETEC, Ctr Electrochem Technol, New Mat Dept Paseo Miramon, San Sebastian 20009, Spain
[2] Univ Basque Country, Polymer Sci & Technol Dept, San Sebastian 20018, Spain
[3] Univ Basque Country, Inst Polymer Mat POLYMAT, San Sebastian 20018, Spain
关键词
polycations; ionic liquids; high performance polymers; polyelectrolytes; hydrophilic polymers;
D O I
10.1002/pola.11015
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Ionic liquids are finding industrial applications as green solvent systems for organic synthesis and in liquid-liquid extractions substituting more-toxic chlorinated solvents. This paper demonstrates an easy method of tuning the solubility of the poly(1-vinyl-3-alkyl-imidazolium) halides by a simple anion-exchange reaction.
引用
收藏
页码:208 / 212
页数:5
相关论文
共 15 条
  • [1] Hydrophobic, highly conductive ambient-temperature molten salts
    Bonhote, P
    Dias, AP
    Papageorgiou, N
    Kalyanasundaram, K
    Gratzel, M
    [J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1168 - 1178
  • [2] Copper(I) mediated living radical polymerisation in an ionic liquid
    Carmichael, AJ
    Haddleton, DM
    Bon, SAF
    Seddon, KR
    [J]. CHEMICAL COMMUNICATIONS, 2000, (14) : 1237 - 1238
  • [3] First example of N-heterocyclic carbenes as catalysts for living polymerization:: Organocatalytic ring-opening polymerization of cyclic esters
    Connor, EF
    Nyce, GW
    Myers, M
    Möck, A
    Hedrick, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) : 914 - 915
  • [4] Freemantle M, 2003, CHEM ENG NEWS, V81, P9
  • [5] Use of ionic liquids for π-conjugated polymer electrochemical devices
    Lu, W
    Fadeev, AG
    Qi, BH
    Smela, E
    Mattes, BR
    Ding, J
    Spinks, GM
    Mazurkiewicz, J
    Zhou, DZ
    Wallace, GG
    MacFarlane, DR
    Forsyth, SA
    Forsyth, M
    [J]. SCIENCE, 2002, 297 (5583) : 983 - 987
  • [6] In situ generation of carbenes:: A general and versatile platform for organocatalytic living polymerization
    Nyce, GW
    Glauser, T
    Connor, EF
    Möck, A
    Waymouth, RM
    Hedrick, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) : 3046 - 3056
  • [7] Expanding the catalytic activity of nucleophilic N-heterocyclic carbenes for transesterification reactions
    Nyce, GW
    Lamboy, JA
    Connor, EF
    Waymouth, RM
    Hedrick, JL
    [J]. ORGANIC LETTERS, 2002, 4 (21) : 3587 - 3590
  • [8] ROGERS RD, 2002, NATO SCI SERIES, P1
  • [9] Cross-linked polymer-ionic liquid composite materials
    Snedden, P
    Cooper, AI
    Scott, K
    Winterton, N
    [J]. MACROMOLECULES, 2003, 36 (12) : 4549 - 4556
  • [10] Poly(3,4-alkylenedioxythiophene)-based supercapacitors using ionic liquids as supporting electrolytes
    Stenger-Smith, JD
    Webber, CK
    Anderson, N
    Chafin, AP
    Zong, KK
    Reynolds, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (08) : A973 - A977