Thermal analysis of copper(h) complexes of general formula [Et4N]2[CuBrnCl4-n]

被引：11

作者：

Styczen, E. ^{[1
]}

Jozwiak, W. K. ^{[2
]}

Gazda, M. ^{[3
]}

Wyrzykowski, D. ^{[1
]}

Warnke, Z. ^{[1
]}

机构：

[1] Univ Gdansk, Fac Chem, PL-80952 Gdansk, Poland

[2] Tech Univ Lodz, Inst Gen & Ecol Chem, PL-90924 Lodz, Poland

[3] Gdansk Univ Technol, Fac Phys & Math, PL-80952 Gdansk, Poland

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2008年 / 91卷 / 03期

关键词：

tetrahalogenocuprates(II); thermal decomposition;

D O I：

10.1007/s10973-007-8689-0

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Thermal decomposition of compounds consisting of tetrahalogenocuprate(II), [CuBrnCl4-n](2-) (n=0-4) anions and a tetraethylarnmonium cation has been studied using TG-FTIR, TG-MS, DTA and DTG techniques. The measurements were carried out in an argon and air atmospheres over the temperature range 293-1073 K. The products of the thermal decomposition were identified by IR and Far Infrared (FIR) spectroscopy as well as X-ray powder diffractometry.

引用

收藏

页码：979 / 984

页数：6

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