Palladium-catalyzed ligand-free and efficient Suzuki-Miyaura reaction of heteroaryl halides with MIDA boronates in water

被引:15
|
作者
Liu, Chun [1 ]
Li, Xinmin [1 ]
Liu, Chao [1 ]
Wang, Xinnan [1 ]
Qiu, Jieshan [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
CROSS-COUPLING REACTIONS; BORONIC ACIDS; CHEMISTRY; PROTOCOL; ESTERS;
D O I
10.1039/c5ra10001a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple and environment-friendly protocol for the palladium-catalyzed ligand-free Suzuki-Miyaura reaction of heteroaryl halides with N-methyliminodiacetic acid (MIDA) boronates is developed. The reaction is performed in water as the sole medium and allows the preparation of a variety of heterobiaryls in excellent yields.
引用
收藏
页码:54312 / 54315
页数:4
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