Synthesis of cholic acid based calixpyrroles and porphyrins

被引：7

作者：

Thi, Thu Huong Nguyen ^{[1
]}

Cardova, Lenka ^{[2
]}

Dvorakova, Michaela ^{[1
]}

Rockova, Dagmar ^{[1
]}

Drasar, Pavel ^{[2
]}

机构：

[1] JE Purkyne Univ Usti Labem, Fac Nat Sci, Dept Chem, Usti Nad Labem 40096, Czech Republic

[2] Prague Inst Chem Technol, Dept Chem Nat Cpds, CR-16628 Prague 6, Czech Republic

来源：

STEROIDS | 2012年 / 77卷 / 8-9期

关键词：

Oligopyrrole macrocycle; Steroidal heterocycle; Chiral receptor; Microwave synthesis; Calix[4]pyrrole; Supramolecular synthon; AGGREGATION; DERIVATIVES; RECEPTORS; CONJUGATE; DYE;

D O I：

10.1016/j.steroids.2012.04.008

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

New cholic acid based calix[4]pyrroles and porphyrins were prepared and their properties were studied. It was confirmed by spectral measurements that the superassembly of 5, 15-bis(3 alpha, 7 alpha, 12 alpha-trihydroxy-5 beta-cholan-24-yl)-10,20-diphenylporphyrin, the best candidate for this study from the conjugates prepared, may be influenced not only by the solvent mixture composition (polar/non-polar component ratio) but by time as well. (c) 2012 Elsevier Inc. All rights reserved.

引用

页码：858 / 863

页数：6

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