Synthesis of cholic acid based calixpyrroles and porphyrins

被引：7
|
作者：
Thi, Thu Huong Nguyen [1 ]
Cardova, Lenka [2 ]
Dvorakova, Michaela [1 ]
Rockova, Dagmar [1 ]
Drasar, Pavel [2 ]
机构：
[1] JE Purkyne Univ Usti Labem, Fac Nat Sci, Dept Chem, Usti Nad Labem 40096, Czech Republic
[2] Prague Inst Chem Technol, Dept Chem Nat Cpds, CR-16628 Prague 6, Czech Republic
来源：
STEROIDS | 2012年 / 77卷 / 8-9期
关键词：
Oligopyrrole macrocycle; Steroidal heterocycle; Chiral receptor; Microwave synthesis; Calix[4]pyrrole; Supramolecular synthon; AGGREGATION; DERIVATIVES; RECEPTORS; CONJUGATE; DYE;
D O I：
10.1016/j.steroids.2012.04.008
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
New cholic acid based calix[4]pyrroles and porphyrins were prepared and their properties were studied. It was confirmed by spectral measurements that the superassembly of 5, 15-bis(3 alpha, 7 alpha, 12 alpha-trihydroxy-5 beta-cholan-24-yl)-10,20-diphenylporphyrin, the best candidate for this study from the conjugates prepared, may be influenced not only by the solvent mixture composition (polar/non-polar component ratio) but by time as well. (c) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码：858 / 863
页数：6
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