The first metal-organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties

被引：135

作者：

Fu, Da-Wei ^{[1
]}

Zhang, Wen ^{[1
]}

Xiong, Ren-Gen ^{[1
,2
]}

机构：

[1] SE Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

DALTON TRANSACTIONS | 2008年 / 30期

关键词：

D O I：

10.1039/b806255b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reaction of H-Imazethapyr (2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)- 5-ethyl3-pyridinecarboxylic acid) with Cd(ClO(4))(2)center dot 6H(2)O offers a diamond-like MOF 1 Cd(Imazethapyr) 2 in which it crystallizes in a non-centrosymmetric space group (Fdd2) belonging to polar point group (C(2v)). MOF 1 displays a strong SHG response, and good ferroelectric and piezoelectric properties.

引用

页码：3946 / 3948

页数：3

共 20 条

[1] Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition [J].

Cui, HengBo ;

Wang, Zheming ;

Takahashi, Kazuyuki ;

Okano, Yoshinori ;

Kobayashi, Hayao ;

Kobayashi, Akiko .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15074-15075

[2]

Fu DW, 2008, DALTON T, P874, DOI 10.1039/b714293e

[3] Dielectric anisotropy of a homochiral trinuclear nickel(II) complex [J].

Fu, Da-Wei ;

Song, Yu-Mei ;

Wang, Guo-Xi ;

Ye, Qiong ;

Xiong, Ren-Gen ;

Akutagawa, Tomoyuki ;

Nakamura, Takayoshi ;

Chan, Philip Wai Hong ;

Huang, Songping D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (17) :5346-+

[4] Crystal structures and magnetic and ferroelectric properties of chiral layered metal-organic frameworks with dicyanamide as the bridging ligand [J].

Gu, Zhi-Guo ;

Zhou, Xin-Hui ;

Jin, Yang-Bo ;

Xiong, Ren-Gen ;

Zuo, Jing-Lin ;

You, Xiao-Zeng .

INORGANIC CHEMISTRY, 2007, 46 (14) :5462-5464

[5] A novel TGS-like inorganic-organic hybrid and a preliminary investigation of its possible ferroelectric behavior [J].

Li, YH ;

Qu, ZR ;

Zhao, H ;

Ye, Q ;

Xing, LX ;

Wang, XS ;

Xiong, RG ;

You, XZ .

INORGANIC CHEMISTRY, 2004, 43 (13) :3768-3770

[6] A mixed-valence coordination polymer featuring two-dimensional ferroelectric order:: {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeC4)}n (Et2dtc- = diethyidithiocarbamate) [J].

Okubo, T ;

Kawajiri, R ;

Mitani, T ;

Shimoda, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (50) :17598-17599

[7] Homochiral laminar europium metal-organic framework with unprecedented giant dielectric anisotropy [J].

Qu, Zhi-Rong ;

Ye, Qiong ;

Zhao, Hong ;

Fu, Da-Wei ;

Ye, Heng-Yun ;

Xiong, Ren-Gen ;

Akutagawa, Tomoyuki ;

Nakamura, Takayoshi .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (11) :3452-3456

[8] Synthesis of novel chiral and acentric coordination polymers by the reaction of zinc or cadmium salts with racemic 3-pyridyl-3-aminopropionic acid [J].

Qu, ZR ;

Zhao, H ;

Wang, YP ;

Wang, XS ;

Ye, QO ;

Li, YH ;

Xiong, RG ;

Abrahams, BF ;

Liu, ZG ;

Xue, ZL ;

You, XZ .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :53-60

[9] The first highly stable homochiral olefin-copper(I) 2D coordination polymer grid based on quinine as building block [J].

Qu, ZR ;

Chen, ZF ;

Zhang, J ;

Xiong, RG ;

Abrahams, BF ;

Xue, ZL .

ORGANOMETALLICS, 2003, 22 (14) :2814-2816

[10] Lead-free piezoceramics [J].

Saito, Y ;

Takao, H ;

Tani, T ;

Nonoyama, T ;

Takatori, K ;

Homma, T ;

Nagaya, T ;

Nakamura, M .

NATURE, 2004, 432 (7013) :84-87

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