The first metal-organic framework (MOF) of Imazethapyr and its SHG, piezoelectric and ferroelectric properties

被引：133
作者：
Fu, Da-Wei [1 ]
Zhang, Wen [1 ]
Xiong, Ren-Gen [1 ,2 ]
机构：
[1] SE Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China
[2] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
来源：
DALTON TRANSACTIONS | 2008年 / 30期
关键词：
D O I：
10.1039/b806255b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal reaction of H-Imazethapyr (2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)- 5-ethyl3-pyridinecarboxylic acid) with Cd(ClO(4))(2)center dot 6H(2)O offers a diamond-like MOF 1 Cd(Imazethapyr) 2 in which it crystallizes in a non-centrosymmetric space group (Fdd2) belonging to polar point group (C(2v)). MOF 1 displays a strong SHG response, and good ferroelectric and piezoelectric properties.
引用
收藏
页码：3946 / 3948
页数：3
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