Cubic-structured tin selenide thin film

被引:37
作者
Nair, P. K. [1 ]
Barrios-Salgado, E. [1 ]
Nair, M. T. S. [1 ]
机构
[1] Univ Nacl Autonoma Mexico Temixco, Inst Energias Renovables, Temixco 62580, Morelos, Mexico
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2016年 / 213卷 / 08期
关键词
chalcogenides; cubic tin selenide; cubic tin sulfide; SnS; SnSe; solar cells; solar energy; thin films; CRYSTALLINE-STRUCTURE; CHEMICAL-DEPOSITION; ZINC BLENDE; SNS; SULFIDE; PHASE; PHOTOVOLTAICS; PRESSURE;
D O I
10.1002/pssa.201533040
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Tin selenide thin film with a simple cubic crystalline structure (SnSe-CUB) of unit cell dimension a = 11.9632 angstrom is obtained via chemical deposition on a tin sulfide (SnS-CUB) thin film base layer of simple cubic structure of a = 11.5873 angstrom. The SnSe-CUB films obtained this way are thermally stable while heating to 300 degrees C. Its optical band gap is 1.4 eV. A thin film of 200 nm in thickness of this material in a solar cell may lead to a light generated current density of 23 mA cm(-2) and a maximum of 29 mA cm(-2). Thin film of SnSe-CUB possesses p-type electrical conductivity of 5 x 10(-5) V-1 cm(-1), which is three orders of magnitude lower than that of SnSe films of orthorhombic crystalline structure. Overall, these characteristics make SnSe-CUB thin film a novel solar cell absorber material. (C) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:2229 / 2236
页数:8
相关论文
共 28 条
  • [1] Synthesis and properties of nanocrystalline π-SnS - a new cubic phase of tin sulphide
    Abutbul, R. E.
    Segev, E.
    Zeiri, L.
    Ezersky, V.
    Makov, G.
    Golan, Y.
    [J]. RSC ADVANCES, 2016, 6 (07) : 5848 - 5855
  • [2] Polymorph-Selective Deposition of High Purity SnS Thin Films from a Single Source Precursor
    Ahmet, Ibbi Y.
    Hill, Michael S.
    Johnson, Andrew L.
    Peter, Laurence M.
    [J]. CHEMISTRY OF MATERIALS, 2015, 27 (22) : 7680 - 7688
  • [3] Polymorphic tin sulfide thin films of zinc blende and orthorhombic structures by chemical deposition
    Avellaneda, David
    Nair, M. T. S.
    Nair, P. K.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (07) : D517 - D525
  • [4] Chemically Deposited SnSe Thin Films: Thermal Stability and Solar Cell Application
    Barrios-Salgado, Enue
    Nair, M. T. S.
    Nair, P. K.
    [J]. ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2014, 3 (08) : Q169 - Q175
  • [5] STRUCTURE AND OPTICAL PROPERTIES OF EPITAXIAL SNTE - SNSE- AND SNS-LAYERS
    BILENKII, BF
    MIKOLAIC.AG
    FREIK, DM
    [J]. PHYSICA STATUS SOLIDI, 1968, 28 (01): : K5 - &
  • [6] Benzyl-substituted tin chalcogenides. Efficient single-source precursors for tin sulfide, tin selenide, and Sn(SxSe1-x) solid solutions
    Boudjouk, P
    Seidler, DJ
    Grier, D
    McCarthy, GJ
    [J]. CHEMISTRY OF MATERIALS, 1996, 8 (06) : 1189 - 1196
  • [7] Phase Stability of the Earth-Abundant Tin Sulfides SnS, SnS2, and Sn2S3
    Burton, Lee A.
    Walsh, Aron
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (45) : 24262 - 24267
  • [8] Thin film solar cell of SnS absorber with cubic crystalline structure
    Garcia-Angelmo, A. R.
    Romano-Trujillo, R.
    Campos-Alvarez, J.
    Gomez-Daza, O.
    Nair, M. T. S.
    Nair, P. K.
    [J]. PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2015, 212 (10): : 2332 - 2340
  • [9] Evolution of crystalline structure in SnS thin films prepared by chemical deposition
    Garcia-Angelmo, Ana Rosa
    Nair, M. T. S.
    Nair, P. K.
    [J]. SOLID STATE SCIENCES, 2014, 30 : 26 - 35
  • [10] Tetrahedral zinc blende tin sulfide nanoand microcrystals
    Greyson, EC
    Barton, JE
    Odom, TW
    [J]. SMALL, 2006, 2 (03) : 368 - 371