Microwave-Assisted Synthesis of Magnetic Hydroxyapatite for Removal of Heavy Metals from Groundwater

被引:56
作者
Elkady, Marwa [1 ,2 ]
Shokry, Hassan [3 ]
Hamad, Hesham [1 ]
机构
[1] ATNMRI, City Sci Res & Technol Applicat SRTA City, Fabricat Technol Dept, Alexandria 21934, New Borg El Ara, Egypt
[2] E JUST, Chem & Petrochem Engn Dept, POB 179, Alexandria 21934, New Borg El Ara, Egypt
[3] ATNMRI, City Sci Res & Technol Applicat SRTA City, Elect Mat Res Dept, Alexandria 21934, New Borg El Ara, Egypt
关键词
Coprecipitation; Heavy metal removal; Magnetic composites; Microwave-assisted synthesis; Nanocomposites; AQUEOUS-SOLUTION; ADSORPTION; NANOPARTICLES; PARAMETERS; ADSORBENT; STRONTIUM; GRAPHENE; PB(II); PHENOL; WASTE;
D O I
10.1002/ceat.201600631
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A simple, fast, and economic methodology to fabricate a highly efficient superparamagnetic Fe3O4/hydroxyapatite nanocomposite (MHAP) was successfully developed. Hydroxyapatite was functionalized with magnetite nanoparticles through coprecipitation-assisted microwave processes to improve the magnetic properties. The synthesized magnetic hybrid adsorbent matrix was investigated by different methods. Transmission electron microscopy demonstrated a good impregnation of Fe3O4 on the hydroxyapatite matrix with uniform morphology. Magnetic hysteresis measurement revealed that MHAP nanocomposites exhibit excellent strong, soft-magnetic properties. The synergistic effect was an evidence for iron and manganese ion removal, enlightening their potentialities in treatment of polluted ground water.
引用
收藏
页码:553 / 562
页数:10
相关论文
共 38 条
[1]   Management of agricultural waste for removal of heavy metals from aqueous solution: adsorption behaviors, adsorption mechanisms, environmental protection, and techno-economic analysis [J].
Abd Elhafez, S. E. ;
Hamad, H. A. ;
Zaatout, A. A. ;
Malash, G. F. .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2017, 24 (02) :1397-1415
[2]   Efficient removal of Cr(VI) from aqueous solution with Fe@Fe2O3 core-shell nanowires [J].
Ai, Zhihui ;
Cheng, Ying ;
Zhang, Lizhi ;
Qiu, Jianrong .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (18) :6955-6960
[3]   Adsorption of phenol on a novel adsorption material PEI/SiO2 [J].
An, Fuqiang ;
Gao, Baojiao .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (03) :1186-1191
[4]   Comparative performance of anodic oxidation and electrocoagulation as clean processes for electrocatalytic degradation of diazo dye Acid Brown 14 in aqueous medium [J].
Bassyouni, D. G. ;
Hamad, H. A. ;
El-Ashtoukhy, E-S. Z. ;
Amin, N. K. ;
Abd El-Latif, M. M. .
JOURNAL OF HAZARDOUS MATERIALS, 2017, 335 :178-187
[5]   Synthesis and characterization of hydroxyapatite nanoparticles impregnated on apple pomace to enhanced adsorption of Pb(II), Cd(II), and Ni(II) ions from aqueous solution [J].
Chand, Piar ;
Pakade, Yogesh B. .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2015, 22 (14) :10919-10929
[6]   Preparation of Fe (core)/SiO2 (shell) composite particles with improved oxidation-resistance [J].
Cheng, Jing ;
Ni, Xiaomin ;
Zheng, Huagui ;
Li, Beibei ;
Zhang, Xiaojun ;
Zhang, Dongen .
MATERIALS RESEARCH BULLETIN, 2006, 41 (08) :1424-1429
[7]   Chemical synthesis of hydroxyapatite/poly(ε-caprolactone) composites [J].
Choi, DW ;
Marra, KG ;
Kumta, PN .
MATERIALS RESEARCH BULLETIN, 2004, 39 (03) :417-432
[8]   The removal of heavy metals in aqueous solution by hydroxyapatite/cellulose composite [J].
Choi, Soohee ;
Jeong, Youngjin .
FIBERS AND POLYMERS, 2008, 9 (03) :267-270
[9]   Mechanism of Pb(II) and methylene blue adsorption onto magnetic carbonate hydroxyapatite/graphene oxide [J].
Cui, Limei ;
Wang, Yaoguang ;
Hu, Lihua ;
Gao, Liang ;
Du, Bin ;
Wei, Qin .
RSC ADVANCES, 2015, 5 (13) :9759-9770
[10]  
Cullity B.D., 1972, Introduction to Magnetic Materials