Interaction between charge-regulated surfaces in the presence of polyelectrolytes

被引：0
|
作者：
Zhmud, B. [1 ]
机构：
[1] Inst Surface Chem YKI, S-11486 Stockholm, Sweden
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / Suppl 1期
关键词：
Electrical Double Layer; Surface Charge Density; Entropy Loss; Polyelectrolyte Chain; Electrical Double Layer Thickness;
D O I：
10.1134/S0036024406130280
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This work gives a brief overview of the backgrounds of the self-consistent mean-field theory as applied to the problem of interaction between charge- regulated surfaces in the presence of polyelectrolytes. A general algorithm for obtaining a self-consistent solution is described, and the asymptotic properties of the solution at close separations are analyzed. Known limitations of the self-consistent field approximation are discussed, highlighting the role of local effects and system equilibration.
引用
收藏
页码：S177 / S184
页数：8
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