Ballistic and diffusive vibrational energy transport in molecules

被引:43
|
作者
Rubtsov, Igor V. [1 ]
Burin, Alexander L. [1 ]
机构
[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2019年 / 150卷 / 02期
基金
美国国家科学基金会;
关键词
LARGE POLYATOMIC-MOLECULES; THERMAL CONDUCTANCE; TEMPERATURE-DEPENDENCE; 2D-IR SPECTROSCOPY; IR SPECTROSCOPY; PEPTIDE HELICES; RELAXATION; FLOW; DYNAMICS; REDISTRIBUTION;
D O I
10.1063/1.5055670
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Energy transport in molecules is essential for many areas of science and technology. Strong covalent bonds of a molecular backbone can facilitate the involvement of the molecule's high-frequency modes in energy transport, which, under certain conditions, makes the transport fast and efficient. We discuss such conditions and describe various transport regimes in molecules, including ballistic, diffusive, directed diffusion, and intermediate regime cases, in light of recently developed experimental and theoretical approaches. Published under license by AIP Publishing.
引用
收藏
页数:19
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