Investigation on the upconversion luminescence in Ho3+/Yb3+ co-doped Ba3Sc4O9 phosphor

被引：41
作者：
Liu, Shuifu [1 ]
Liu, Songbin [1 ]
Ming, Hong [1 ]
Hou, Dejian [1 ]
You, Weixiong [3 ]
Ye, Xinyu [1 ,2 ]
机构：
[1] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Peoples R China
[2] Natl Engn Res Ctr Ion Rare Earth, Ganzhou 341000, Peoples R China
[3] Jiangxi Univ Sci & Technol, Sch Mat Sci & Engn, Ganzhou 341000, Peoples R China
来源：
MATERIALS RESEARCH BULLETIN | 2018年 / 98卷
关键词：
Upconversion; Phosphor; Ba3Sc4O9; Energy transfer; ENERGY-TRANSFER; GREEN; NANOCRYSTALS; EMISSION; HO3+; PHOTOLUMINESCENCE; TEMPERATURE; SCANDATE; INTENSE; SIZE;
D O I：
10.1016/j.materresbull.2017.10.025
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of Ba3Sc4O5:Ho3+/Yb3+ phosphors were synthesized by a high-temperature solid-state reaction method. The phase purity and upconversion luminescence were characterized by X-ray diffraction and photoluminescence spectroscopy. The sintering temperature and doping concentrations were optimized to obtain the strongest emission intensity. Under 980 nm laser diode excitation, the green (545 nm, F-5(4)/S-5(2) -> I-5(8)) and red (665 nm, F-5(5) -> I-5(8)) emissions were observed. The cross-relaxation and back-energy-transfer processes play an important role to adjust the emission intensity ratio of Green/Red at different dopant concentrations. Based on the energy level diagrams, the energy transfer mechanisms are investigated in detail according to the analysis of pump power dependence and luminescence decay curves. The upconversion luminescence properties of the phosphor were evaluated and the results show good color monochromaticity and relatively high upconversion luminescence intensity. The Ba3Sc4O5:Ho3+/Yb3+ can be a good candidate for green upconversion material in display fields and fluorescent labeling.
引用
收藏
页码：187 / 193
页数：7
相关论文
共 42 条
[1]   Energy transfer based NIR to visible upconversion: Enhanced red luminescence from Yb3+/Ho3+ co-doped tellurite glass [J].
Balaji, Sathravada ;
Mandal, Ashis K. ;
Annapurna, K. .
OPTICAL MATERIALS, 2012, 34 (11) :1930-1934
[2]  
Bragg WH, 1913, P R SOC LOND A-CONTA, V88, P428, DOI 10.1098/rspa.1913.0040
[3]   Combinatorial Discovery of Lanthanide-Doped Nanocrystals with Spectrally Pure Upconverted Emission [J].
Chan, Emory M. ;
Han, Gang ;
Goldberg, Joshua D. ;
Gargas, Daniel J. ;
Ostrowski, Alexis D. ;
Schuck, P. James ;
Cohen, Bruce E. ;
Milliron, Delia J. .
NANO LETTERS, 2012, 12 (07) :3839-3845
[4]   Synthesis and Upconversion Luminescence of Nanoparticles Y2O3 and Gd2O3 Co-doped with Yb3+ and Er3+ [J].
Chavez, Dalia H. ;
Contreras, Oscar E. ;
Hirata, Gustavo A. .
NANOMATERIALS AND NANOTECHNOLOGY, 2016, 6
[5]   Water detection through Nd3+-sensitized photon upconversion in core-shell nanoarchitecture [J].
Chen, Daqin ;
Xu, Min ;
Huang, Ping ;
Ma, Mengfan ;
Ding, Mingye ;
Lei, Lei .
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (22) :5434-5443
[6]   Nd3+-Sensitized Ho3+ Single-Band Red Upconversion Luminescence in Core Shell Nanoarchitecture [J].
Chen, Daqin ;
Liu, Lu ;
Huang, Ping ;
Ding, Mingye ;
Zhong, Jiasong ;
Ji, Zhenguo .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (14) :2833-2840
[7]   Upconverter solar cells: materials and applications [J].
de Wild, J. ;
Meijerink, A. ;
Rath, J. K. ;
van Sark, W. G. J. H. M. ;
Schropp, R. E. I. .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (12) :4835-4848
[8]   Energy transfer in lanthanide upconversion studies for extended optical applications [J].
Dong, Hao ;
Sun, Ling-Dong ;
Yan, Chun-Hua .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (06) :1608-1634
[9]   Visible upconversion in rare earth ion-doped Gd2O3 nanocrystals [J].
Guo, Hai ;
Dong, Ning ;
Yin, Min ;
Zhang, Weiping ;
Lou, Liren ;
Xia, Shangda .
Journal of Physical Chemistry B, 2004, 108 (50) :19205-19209
[10]   Green and red upconversion luminescence in Er3+-doped and Er3+/Yb3+-codoped SrTiO3 ultrafine powders [J].
Guo, Hai ;
Dong, Ning ;
Yin, Min ;
Zhang, Weiping ;
Lou, Liren ;
Xia, Shangda .
JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 415 (1-2) :280-283
12345