Anion-templated synthesis and structural characterisation of Ni/Pd-containing metalla-macrocycles

被引：41

作者：

Doxiadi, E ^{[1
]}

Vilar, R ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

POLYHEDRON | 2003年 / 22卷 / 22期

关键词：

metalla-macrocycles; templating agents; palladium and nickel complexes; triphenylphosphine; anion template; hydrogen bonding;

D O I：

10.1016/S0277-5387(03)00435-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the precursor [Pd(PPh3)(2)(Hatu)][CF3SO3](2) (1) and the anion-templated syntheses of the nickel/palladium metalla-macrocycles [Pd2Ni2(atu)(4)(PPh2R)(4)X](3+) (R = Ph, X = I, 2; R = Py, X = Cl, 3; atu = deprotonated amidinothiourea) are herein reported. The three new compounds have been structurally characterised and, for 1 and 3, interesting intermolecular interactions leading to dimers and extended structures in the solid state, respectively, have been observed. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：2991 / 2998

页数：8