Progress in the development of well-defined ethylene-vinyl halide polymers

被引:16
作者
Boz, Emine
Wagener, Kenneth B. [1 ]
机构
[1] Univ Florida, George & Josephine Butler Polymer Res Lab, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Macromol Sci & Engn, Dept Chem, Gainesville, FL 32611 USA
关键词
polyethylene; PVC; ethylene vinyl halide; olefin metathesis polymerization; reductive dehalogenation; polymer crystallization;
D O I
10.1080/15583720701638310
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Here progress in the development of well-defined halogen containing polyolefins is described. A comparison of industrially relevant examples is given with attention to the influence of the halogen type and content on the thermal and crystalline properties and the resultant structure-function relationships in the context of application. A more detailed account of the fundamental basis of such structure-function relationships is given through a discussion of the various ethylene vinyl halide copolymers that have been reported.
引用
收藏
页码:511 / 541
页数:31
相关论文
共 127 条
[61]   Monoclinic crystallites in ethylene copolymers detected by solid-state NMR and X-ray diffraction [J].
Hu, WG ;
Sirota, EB .
MACROMOLECULES, 2003, 36 (14) :5144-5149
[62]  
Humphrey JS, 2003, ENCY POLYM SCI TECHN, V4, P510
[63]   DIE GLASTEMPERATUR VON COPOLYMEREN [J].
ILLERS, KH .
KOLLOID-ZEITSCHRIFT AND ZEITSCHRIFT FUR POLYMERE, 1963, 190 (01) :16-&
[64]  
IWAMICHI H, 1974, Patent No. 74027108
[65]   TRI-NORMAL-BUTYLTIN HYDRIDE REDUCTION OF POLYVINYL-CHLORIDE) - KINETICS OF DECHLORINATION FOR 2,4-DICHLOROPENTANE AND 2,4,6-TRICHLOROHEPTANE [J].
JAMEISON, FA ;
SCHILLING, FC ;
TONELLI, AE .
MACROMOLECULES, 1986, 19 (08) :2168-2173
[66]  
Jungnickel B.-J, 1996, POLYM MAT ENCY, V9, P7115
[67]  
Kattas L, 2000, MODERN PLASTICS HDB, V4th
[69]   HALOGENATION OF POLYETHYLENE SINGLE CRYSTALS [J].
KELLER, A ;
WINSLOW, FH ;
MATREYEK, W .
JOURNAL OF POLYMER SCIENCE, 1962, 62 (174) :291-&
[70]  
KERBOW DL, 1996, POLYM MAT ENCY, V9, P6884