Syntheses, crystal structures, and spectral properties of Mn(II) and Co(II) complexes with 3-(p-chlorophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole

被引：18

作者：

Zhao, Jian ^{[1
]}

Cheng, Hui-Min ^{[1
]}

Shen, Guo-Ping ^{[1
]}

Xu, Yan ^{[1
]}

Zhu, Dun-Ru ^{[1
]}

机构：

[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Coll Chem & Chem Engn, Nanjing 210009, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 06期

关键词：

Syntheses; Triazole; Crystal structures; Manganese(II) complex; Cobalt(II) complex; DINUCLEAR NICKEL(II) COMPLEX; SPIN-CROSSOVER; MAGNETIC-PROPERTY; ELECTROSPRAY-IONIZATION; MASS-SPECTROMETRY; METAL-COMPLEXES; MONONUCLEAR; LIGANDS;

D O I：

10.1080/00958972.2011.558897

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new complexes, trans-[MnL2(NCS)(2)] (1) and trans-[CoL2(H2O)(EtOH)](ClO4)(2)center dot H2O (2) with asymmetrical triaryltriazole ligands [L = 3-(p-chlorophenyl)-4-(p-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole], have been synthesized and characterized by elemental analysis, FT-IR, ESI-MS, and single-crystal X-ray diffraction. In the complexes each L adopts a chelating bidentate mode via the nitrogen of pyridyl and triazole. Both complexes have a similar distorted octahedral core with two NCS- ions in the trans position in 1, while one H2O and one EtOH are present in the axial sites in 2.

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页码：942 / 951

页数：10

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