Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates

被引：59

作者：

Chierchia, Matteo ^{[1
]}

Law, Chunyin ^{[1
]}

Morken, James P. ^{[1
]}

机构：

[1] Boston Coll, Dept Chem, 2609 Beacon St, Chestnut Hill, MA 02467 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 39期

关键词：

asymmetric catalysis; boron; cross coupling; nickel; BORANE INTRAMOLECULAR COMPLEXES; VINYL BORONATE COMPLEXES; POTASSIUM T-BUTOXIDE; CONVENIENT PROCEDURE; ASYMMETRIC-SYNTHESIS; HECK REACTION; ATE COMPLEXES; ALPHA-OLEFINS; ALKYL-GROUPS; N-OXIDE;

D O I：

10.1002/anie.201706719

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.

引用

页码：11870 / 11874

页数：5

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