Copper-Containing Catalyst with Fixed Active Component on an Alumina-Silica Carrier

被引:4
作者
Vanchurin, V. I. [1 ]
Dzhumamukhamedov, D. Sh. [1 ,2 ]
Popova, N. A. [1 ]
机构
[1] DI Mendeleev Russian Chem Technol Univ, Moscow, Russia
[2] GazokhimTekhno JSC, Moscow, Russia
关键词
copper-containing catalysts; silica; alumina-silica carriers; dehydration of cyclohexanol; thermal stability;
D O I
10.1007/s10717-015-9698-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
It was found that the low thermal stability of commercial copper-containing catalyst (BASF Company) is associated with the chemical non-fixing of the active component on the surface of the silica carrier, while the degradation of its strength is due to the phase transition of the SiO2 carrier (alpha-quartz) into alpha-cristobalite. A thermally stable copper-containing catalyst MAK-K with an active component firmly bound with an alumina-silica carrier is proposed and studied. Experimental tests of the catalysts for thermal stability show that at 350A degrees C the relative activity of the catalyst N3-11 decreases by 41%, while the relative activity of the catalyst MAK-K changes by only 15%.
引用
收藏
页码:405 / 409
页数:5
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