Enabling High-Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte

被引:240
作者
Jie, Yulin [1 ]
Liu, Xiaojing [1 ,2 ]
Lei, Zhanwu [1 ]
Wang, Shiyang [1 ]
Chen, Yawei [1 ]
Huang, Fanyang [1 ]
Cao, Ruiguo [1 ]
Zhang, Genqiang [1 ]
Jiao, Shuhong [1 ]
机构
[1] Univ Sci & Technol China, CAS Key Lab Mat Energy Convers, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
[2] Shandong Univ, Inst Mol Sci & Engn, Qingdao 266237, Peoples R China
基金
中国国家自然科学基金;
关键词
electrode materials; high voltage; lithium metal batteries; lithium solvate sheath; HIGH-ENERGY; DONOR; LI; ANODE;
D O I
10.1002/anie.201914250
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Lithium metal is an ideal electrode material for future rechargeable lithium metal batteries. However, the widespread deployment of metallic lithium anode is significantly hindered by its dendritic growth and low Coulombic efficiency, especially in ester solvents. Herein, by rationally manipulating the electrolyte solvation structure with a high donor number solvent, enhancement of the solubility of lithium nitrate in an ester-based electrolyte is successfully demonstrated, which enables high-voltage lithium metal batteries. Remarkably, the electrolyte with a high concentration of LiNO3 additive presents an excellent Coulombic efficiency up to 98.8 % during stable galvanostatic lithium plating/stripping cycles. A full-cell lithium metal battery with a lithium nickel manganese cobalt oxide cathode exhibits a stable cycling performance showing limited capacity decay. This approach provides an effective electrolyte manipulation strategy to develop high-voltage lithium metal batteries.
引用
收藏
页码:3505 / 3510
页数:6
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