Mononuclear gold(I) complex of a chiral tetra(tertiary phosphine).: Crystal and molecular structure of [T-4-(RP*,RP*)]-(±)-1,2-bis[(2-diphenylphosphinophenyl)methylphosphino]benzene-P,P′,P",P′" gold(I) hexafluorophosphate

被引：3
作者：
Chatterjee, S [1 ]
Moore, FKE
Salem, G
Waring, P
Willis, AC
机构：
[1] Australian Natl Univ, The Fac, Dept Chem, Canberra, ACT 0200, Australia
[2] Australian Natl Univ, John Curtin Sch Med Res, Canberra, ACT 0200, Australia
[3] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 24期
关键词：
D O I：
10.1039/b007363f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A mononuclear tetra(tertiary phosphine)gold(I) complex has been isolated via the reaction of (R-P*,R-P*)-1,2-bis[(2-dimethylphosphinophenyl)methylphosphino]benzene, (R-P*,R-P*)-TPP4, with NBu4n[AuI2] in ethanol followed by metathesis with aqueous NH4PF6; as confirmed by a crystal structure determination of [Au{(R-P*,R-P*)-TPP4}]PF6.
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页码：4487 / 4489
页数：3
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