Synthesis and structure of the binuclear 1:1 silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenylphosphine complex

被引：6

作者：

bin Othman, AH

Effendy

Skelton, BW

White, AH ^{[1
]}

机构：

[1] Univ Western Australia, Crawley 6009, Australia

[2] Univ Kebangsaan Malaysia, Jabatan Kimia, Bangi 43600, Selangor, Malaysia

[3] FPMIPA IKIP Malang, Jurusan Pendidikan Kimia, Malang 65145, Indonesia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2003年 / 56卷 / 07期

关键词：

D O I：

10.1071/CH02135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.

引用

页码：719 / 721

页数：3

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