Synthesis and structure of the binuclear 1:1 silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenylphosphine complex

被引：6
作者：
bin Othman, AH
Effendy
Skelton, BW
White, AH [1 ]
机构：
[1] Univ Western Australia, Crawley 6009, Australia
[2] Univ Kebangsaan Malaysia, Jabatan Kimia, Bangi 43600, Selangor, Malaysia
[3] FPMIPA IKIP Malang, Jurusan Pendidikan Kimia, Malang 65145, Indonesia
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 2003年 / 56卷 / 07期
关键词：
D O I：
10.1071/CH02135
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A room-temperature single-crystal X-ray structure determination of the 1:1 adduct of silver(I) 2-hydroxy-3,5-dinitrobenzoate/triphenyl-phosphine (AgL/PPh3) was recorded, showing it to be a binuclear centrosymmetric system with the silver atoms bridged by one of the carboxy oxygen atoms of each ligand, [(PPh3)Ag(mu-O)(2)Ag(PPh3)] as in the parent acetate; the phenolic oxygen, retaining its protonation, is hydrogen bonded within the ligand to the other feebly chelating carboxylate oxygen.
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页码：719 / 721
页数：3
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