Gold nanoparticles in mesoporous materials showing catalytic selective oxidation cyclohexane using oxygen

被引：62
作者：
Lü, GM
Ji, D
Qian, G
Qi, YX [1 ]
Wang, XL
Suo, JS
机构：
[1] Natl Engn Res Ctr Fine Petrochem Intermediates, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
来源：
APPLIED CATALYSIS A-GENERAL | 2005年 / 280卷 / 02期
关键词：
gold; mesoporous materials; selective oxidation; cyclohexane;
D O I：
10.1016/j.apcata.2004.10.034
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The nano-Au supported mesoporous materials were prepared and characterized by XRD, N-2 adsorption/desorption, UV-vis, XPS, and ICP-AES. The liquid-phase selective oxidation cyclohexane to cyclohexanol and cyclohexanone over nano-Au in mesoporous materials catalyst was carried out in a solvent-free system, in which oxygen was the only oxidant and the reaction conditions are very moderate. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：175 / 180
页数：6
相关论文
共 21 条
[1]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[2]   From microporous to mesoporous molecular sieve materials and their use in catalysis [J].
Corma, A .
CHEMICAL REVIEWS, 1997, 97 (06) :2373-2419
[3]   Influence of the preparation of Au/Al2O3 on CH4 oxidation activity [J].
Grisel, RJH ;
Kooyman, PJ ;
Nieuwenhuys, BE .
JOURNAL OF CATALYSIS, 2000, 191 (02) :430-437
[4]  
Kaliaguine S., 2003, APPL CATAL A-GEN, V253, P545, DOI DOI 10.1016/S0926-860X(03)00195-9
[5]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[6]   LOW-TEMPERATURE CO OXIDATION OVER AU/TIO2 AND AU/SIO2 CATALYSTS [J].
LIN, SD ;
BOLLINGER, M ;
VANNICE, MA .
CATALYSIS LETTERS, 1993, 17 (3-4) :245-262
[7]   Size and temperature dependence of the plasmon absorption of colloidal gold nanoparticles [J].
Link, S ;
El-Sayed, MA .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (21) :4212-4217
[8]  
MARCELL RL, 1967, Patent No. 3317614
[9]  
Musser M. T, 1987, ENCY IND CHEM, P217
[10]   Hydrogenation of 1,3-butadiene and of crotonaldehyde over highly dispersed Au catalysts [J].
Okumura, M ;
Akita, T ;
Haruta, M .
CATALYSIS TODAY, 2002, 74 (3-4) :265-269
123