Synthesis and structure of an asymmetrical sila[1]magnesocenophane

被引:0
|
作者
Bischoff, Inga-Alexandra [1 ]
Morgenstern, Bernd [1 ]
Schaefer, Andre [1 ]
机构
[1] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Campus Saarbrucken, D-66123 Saarbrucken, Germany
关键词
magnesium; magnesocenophanes; metallocenes; metallocenophanes; slipped sandwich structure; STRAINED METALLOCENOPHANES; COMPLEXES; POLYMERIZATION; DYNAMICS;
D O I
10.1515/znb-2021-0152
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structure of an asymmetrical sila[1]magnesocenophane, featuring a cyclopentadienyl and a tetramethylcyclopentadienyl group, are reported. The compound was obtained as a bis(tetrahydrofuran) adduct and exhibits a slipped sandwich structure in the solid state.
引用
收藏
页码:95 / 98
页数:4
相关论文
共 50 条
  • [41] 1-Organosulfonyl-2-sila-5-piperazinones: Synthesis, molecular and crystal structure, and chemical transformations into 2-aminoacid derivatives
    Shipov, Alexandr G.
    Kramarova, Eugenia P.
    Fang, Huntse
    Arkhipov, Dmitry E.
    Nikolin, Alexey A.
    Bylikin, Sergey Yu.
    Negrebetsky, Vadim V.
    Korlyukov, Alexandr A.
    Voronina, Natalia A.
    Bassindale, Alan R.
    Taylor, Peter G.
    Baukov, Yuri I.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 741 : 114 - 121
  • [42] REACTIVITY OF 1,1-DIMETHYL-1-SILA-3-CYCLOPENTENE - SYNTHESIS OF BUT-3-ENYLDIMETHYLCHLOROSILANE
    CALAS, R
    BOURGEOI.P
    DUNOGUES, J
    PISCIOTT.F
    ARREGUY, B
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE II-CHIMIE MOLECULAIRE ORGANIQUE ET BIOLOGIQUE, 1974, (11): : 2556 - 2558
  • [43] SILICON HETEROCYCLIC COMPOUNDS .I. SYNTHESIS OF 3-SILA-1-HETEROCYCLOHEXANES
    FESSENDEN, RJ
    COON, MD
    JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (06): : 1607 - &
  • [44] SILICON HETEROCYCLIC COMPOUNDS .2. SYNTHESIS OF 3-SILA-1-HETEROCYCLOHEPTANES
    FESSENDEN, RJ
    COON, MD
    JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (09): : 2499 - &
  • [45] 1-sila-[1]ferrocenophanes, structure and reactivity - Ring-opening by reactions with boron halides
    Wrackmeyer, B
    Ayazi, A
    Milius, W
    Herberhold, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 682 (1-2) : 180 - 187
  • [46] On asymmetrical synthesis.
    Fischer, E
    Slimmer, M
    SITZUNGSBERICHTE DER KONIGLICH PREUSSISCHEN AKADEMIE DER WISSENSCHAFTEN, 1902, : 597 - 610
  • [47] ASYMMETRICAL SYNTHESIS WITH ENZYMES
    GAIS, HJ
    HEMMERLE, H
    CHEMIE IN UNSERER ZEIT, 1990, 24 (05) : 239 - 248
  • [48] SYNTHESIS OF ASYMMETRICAL BISPHOSPHINYLETHANE
    GLOEDE, J
    JOURNAL FUR PRAKTISCHE CHEMIE, 1972, 314 (02): : 281 - &
  • [49] 1,1-DIMETHOXY-1-SILA-2-OXAAZACYCLANES IN THE SYNTHESIS OF FUNCTIONALLY-SUBSTITUTED SILATRANES
    KRAMAROVA, EP
    MAMAEVA, EA
    SHIPOV, AG
    BAUKOV, YI
    ZHURNAL OBSHCHEI KHIMII, 1993, 63 (06): : 1435 - 1436
  • [50] ON SYNTHESIS OF ASYMMETRICAL CURCUMINOIDES
    MANN, G
    BEYER, L
    ARRIETA, A
    ZEITSCHRIFT FUR CHEMIE, 1987, 27 (05): : 172 - 173