Synthesis and structure of an asymmetrical sila[1]magnesocenophane

被引:0
|
作者
Bischoff, Inga-Alexandra [1 ]
Morgenstern, Bernd [1 ]
Schaefer, Andre [1 ]
机构
[1] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Campus Saarbrucken, D-66123 Saarbrucken, Germany
关键词
magnesium; magnesocenophanes; metallocenes; metallocenophanes; slipped sandwich structure; STRAINED METALLOCENOPHANES; COMPLEXES; POLYMERIZATION; DYNAMICS;
D O I
10.1515/znb-2021-0152
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structure of an asymmetrical sila[1]magnesocenophane, featuring a cyclopentadienyl and a tetramethylcyclopentadienyl group, are reported. The compound was obtained as a bis(tetrahydrofuran) adduct and exhibits a slipped sandwich structure in the solid state.
引用
收藏
页码:95 / 98
页数:4
相关论文
共 50 条
  • [31] SYNTHESIS OF 1,1-DIMETHYL-1-SILA-3-CYCLOPENTENE BY METATHESIS REACTION OF DIMETHYLDIALLYLSILANE
    FINKELSHTEIN, ES
    PORTNYKH, EB
    USHAKOV, NV
    VDOVIN, BM
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1979, 28 (02): : 441 - 441
  • [32] SYNTHESIS OF 1,1-DIETHOXY-2-(TRIMETHYLSILYL)-1-SILA-2-AZACYCLOPENTANE
    TSAI, TT
    MARSHALL, CJ
    JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (11): : 3676 - &
  • [33] SILA-RETINOL - THE 1ST SILA-SUBSTITUTED VITAMIN
    MUNSTEDT, R
    WANNAGAT, U
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 322 (01) : 11 - 24
  • [35] Studies on asymmetrical induction I Announcement - Asymmetrical synthesis and asymmetrical induction
    McKenzie, A
    Mitchell, AG
    BIOCHEMISCHE ZEITSCHRIFT, 1929, 208 : 456 - 470
  • [36] Asymmetrical vesicles: convenient in situ RAFT synthesis and controllable structure determination
    Song, Zefeng
    He, Xin
    Gao, Chengqiang
    Khan, Habib
    Shi, Pengfei
    Zhang, Wangqing
    POLYMER CHEMISTRY, 2015, 6 (36) : 6563 - 6572
  • [37] SYNTHESIS OF ORGANOMETALLIC SULTONES BY SULFONATION OF SILA AND GERMACYCLOBUTANES
    DUBAC, J
    MAZEROLL.P
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1969, (10): : 3608 - &
  • [38] Synthesis, structure and material properties of thiopyranylidene-based asymmetrical squaraines
    Xiao, Qi
    Yang, Shuo
    Wang, Rong
    Zhang, Yuan
    Zhang, Handong
    Zhou, Huiqiong
    Li, Zhong'an
    DYES AND PIGMENTS, 2018, 154 : 137 - 144
  • [39] Synthesis of a new asymmetrical ether diamine with aromatic structure and related polyimide
    Shao, Yu
    Li, Yan Feng
    Wang, Xiao Long
    Zhang, Shu Jiang
    Zhao, Xin
    Ma, Tao
    CHINESE CHEMICAL LETTERS, 2006, 17 (05) : 635 - 636
  • [40] Synthesis and studies of a sila-allyl anion
    Maddelena, Michael R.
    Winchester, William R.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247