Synthesis and structure of an asymmetrical sila[1]magnesocenophane

被引:0
|
作者
Bischoff, Inga-Alexandra [1 ]
Morgenstern, Bernd [1 ]
Schaefer, Andre [1 ]
机构
[1] Saarland Univ, Fac Nat Sci & Technol, Dept Chem, Campus Saarbrucken, D-66123 Saarbrucken, Germany
关键词
magnesium; magnesocenophanes; metallocenes; metallocenophanes; slipped sandwich structure; STRAINED METALLOCENOPHANES; COMPLEXES; POLYMERIZATION; DYNAMICS;
D O I
10.1515/znb-2021-0152
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structure of an asymmetrical sila[1]magnesocenophane, featuring a cyclopentadienyl and a tetramethylcyclopentadienyl group, are reported. The compound was obtained as a bis(tetrahydrofuran) adduct and exhibits a slipped sandwich structure in the solid state.
引用
收藏
页码:95 / 98
页数:4
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